Chirality transfer through helical motifs in coordination compounds

被引：91

作者：

He, Cheng

Zhao, Yonggang

Guo, Dong ^{[1
]}

Lin, Zhihua

Duan, Chunying

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China

[2] Wuhan Inst Technol, Sch Mat Sci & Engn, Wuhan 430073, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 22卷 / 22期

关键词：

helical structures; chirality; building intermediates; conformational chirality;

D O I：

10.1002/ejic.200700360

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Helicates obtained by self-assembly have initiated a revolution from classical coordination chemistry to extensive supramolecular concepts. The design of helicates will be described, and the structural features that are necessary for chirality transfer, as well as the extension of chirality from one dimensional to three-dimensional chiral polymers in complicated chiral architectures will also be addressed. Chiral assembly by using achiral components has been given con-siderable attention in this review paper. The understanding of the essential processes and mechanisms in the chiral assembly on the basis of helicate supramolecular structures is a fundamental study in a variety of disciplines ranging from biology to materials science. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).

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收藏

页码：3451 / 3463

页数：13

相关论文

共 119 条

[21] Chiral noninterpenetrated (10,3)-a net in the crystal structure of Ag(I) and bisthioether [J].

Bu, XH ;

Chen, W ;

Du, M ;

Biradha, K ;

Wang, WZ ;

Zhang, RH .

INORGANIC CHEMISTRY, 2002, 41 (02) :437-+

[22] Self-assembly of a stereoselective trinuclear sodium/lithium triple helix [J].

Capó, M ;

Saá, JM ;

Alvarez, A .

CHEMICAL COMMUNICATIONS, 2002, (17) :1982-1983

[23] A SINGLE STRANDED DIRUTHENIUM(II) HELICAL COMPLEX [J].

CATHEY, CJ ;

CONSTABLE, EC ;

HANNON, MJ ;

TOCHER, DA ;

WARD, MD .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (08) :621-623

[24] Single-strand helical complexes constructed from 2-pyridinyl-3-pyridinylmethanone: tuning the helical pitch length by variation of metal cation and/or counter anion [J].

Chen, XD ;

Mak, TCW .

DALTON TRANSACTIONS, 2005, (22) :3646-3652

[25] Controlled generation of heterochiral or homochiral coordination polymer: helical conformational polymorphs and argentophilicityinduced spontaneous resolution [J].

Chen, XD ;

Du, M ;

Mak, TCW .

CHEMICAL COMMUNICATIONS, 2005, (35) :4417-4419

[26] Using noncovalent intra-strand and inter-strand interactions to prescribe helix formation within a metallo-supramolecular system [J].

Childs, LJ ;

Pascu, M ;

Clarke, AJ ;

Alcock, NW ;

Hannon, ML .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (17) :4291-4300

[27] The 'Trinity' helix:: synthesis and structural characterisation of a C3-symmetric tris-bidentate ligand and its coordination to Ag(I) [J].

Conerney, B ;

Jensen, P ;

Kruger, PE ;

MacGloinn, C .

CHEMICAL COMMUNICATIONS, 2003, (11) :1274-1275

[28] Interlocked chiral nanotubes assembled from quintuple helices [J].

Cui, Y ;

Lee, SJ ;

Lin, WB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (20) :6014-6015

[29] A homochiral triple helix constructed from an axially chiral bipyridine [J].

Cui, Y ;

Ngo, HL ;

Lin, WB .

CHEMICAL COMMUNICATIONS, 2003, (12) :1388-1389

[30] Hierarchical assembly of homochiral porous solids using coordination and hydrogen bonds [J].

Cui, Y ;

Ngo, HL ;

White, PS ;

Lin, WB .

INORGANIC CHEMISTRY, 2003, 42 (03) :652-654

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