Isolation and characterisation of bis(oxahomo)fullerene derivatives of C60F18

被引：21

作者：

Boltalina, OV

de La Vaissière, B

Lukonin, AY

Fowler, PW

Abdul-Sada, AK

Street, JM

Taylor, R ^{[1
]}

机构：

[1] Univ Sussex, CPES Sch, Chem Lab, Brighton BN1 9QJ, E Sussex, England

[2] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

[3] Univ Exeter, Sch Chem, Exeter EX4 4QD, Devon, England

[4] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 2001年 / 04期

关键词：

D O I：

10.1039/b007935i

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

From the products of the reaction of [60]fullerene with K2PtF6 under vacuum at 465 degreesC we have isolated seven isomers of C60F18O2, and characterized them by EI mass spectrometry, IR and F-19 NMR spectroscopy (both 1 D and 2 D). Comparison with data for mono-oxides and the observed lack of connectivity between the fluorines attached to carbons adjacent to oxygen, indicate that these compounds are diethers with oxygen inserted between fluorinated carbons. Structures proposed on the basis of the NMR spectra and semiempirical calculations are found to be consistent with HPLC retention times.

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页码：550 / 556

页数：7

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