RING EXPANSION OF THE FULLERENE CORE BY HIGHLY REGIOSELECTIVE FORMATION OF DIAZAFULLEROIDS

被引：150

作者：

GROSSER, T

PRATO, M

LUCCHINI, V

HIRSCH, A

WUDL, F

机构：

[1] INST ORGAN CHEM,D-76131 KARLSRUHE,GERMANY

[2] DIPARTIMENTO SCI FARMACEUT,TRIESTE,ITALY

[3] DIPARTIMENTO SCI AMBIENTALI,VENICE,ITALY

[4] INST POLYMERS & ORGAN SOLIDS,SANTA BARBARA,CA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 12期

关键词：

AZIDES; FULLERENES; NITROGEN COMPOUNDS;

D O I：

10.1002/anie.199513431

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fullerenes with enlarged openings such as diazafulleroid 1 are obtained by twofold addition of azides to C60. Even after cleavage of the two 5–6 bonds and introduction of the imino bridges, the π‐electron system of C60 remains intact. Compound 1 contains three seven‐membered rings and one eleven‐membered ring, and may hold the key to the synthesis of endohedral fullerenes under mild conditions. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1343 / 1345

页数：3

共 19 条

[1] DIEDERICH F, 1994, CHEM SOC REV, P243
[2] REGIOCHEMISTRY OF THE BISOSMYLATION OF C-60 - ORTHO, META, AND PARA IN 3-DIMENSIONS
HAWKINS, JM
MEYER, A
LEWIS, TA
BUNZ, U
NUNLIST, R
BALL, GE
EBBESEN, TW
TANIGAKI, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (20) : 7954 - 7955
[3] Henderson C. C., 1994, ANGEW CHEM, V706, P803
[4] C60H4 - KINETICS AND THERMODYNAMICS OF MULTIPLE ADDITION TO C-60
HENDERSON, CC
ROHLFING, CM
ASSINK, RA
CAHILL, PA
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (07): : 786 - 788
[5] FULLERENE CHEMISTRY IN 3 DIMENSIONS - ISOLATION OF 7 REGIOISOMERIC BISADDUCTS AND CHIRAL TRISADDUCTS OF C-60 AND DI(ETHOXYCARBONYL)METHYLENE
HIRSCH, A
LAMPARTH, I
KARFUNKEL, HR
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (04): : 437 - 438
[6] REGIOCHEMISTRY OF MULTIPLE ADDITIONS TO THE FULLERENE CORE - SYNTHESIS OF A T-H-SYMMETRICAL HEXAKISADDUCT OF C-60 WITH BIS(ETHOXYCARBONYL)METHYLENE
HIRSCH, A
LAMPARTH, I
GROSSER, T
KARFUNKEL, HR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (20) : 9385 - 9386
[7] Hirsch A, 1994, CHEM FULLERENES, DOI DOI 10.1002/9783527619214
[8] HIRSCH A, 1994, ANGEW CHEM, V106, P453
[9] ISAACS L, 1994, ANGEW CHEM INT EDIT, V33, P2434
[10] ISAACS L, 1994, ANGEW CHEM, V106, P2435

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