Synthesis of a new stable and water-soluble tris(4-hydroxysulfonyl-tetrachlorophenyl)methyl radical with selective oxidative capacity

被引：11

作者：

Antonio Mesa, Juan ^{[1
]}

Velazquez-Palenzuela, Amado ^{[2
]}

Brillas, Enric ^{[2
]}

Lluis Torres, Josep ^{[1
]}

Julia, Luis ^{[1
]}

机构：

[1] CSIC, Inst Quim Avancada Catalunya, Dept Quim Biol & Modelitzacio Mol, ES-08034 Barcelona, Spain

[2] Univ Barcelona, Dept Quim Fis, E-08028 Barcelona, Spain

来源：

TETRAHEDRON | 2011年 / 67卷 / 17期

关键词：

Free radical; Radical-scavenging; Chemosensor; Electron paramagnetic resonance; ELECTRON-TRANSFER CAPACITY; CARBON FREE-RADICALS; ANTIOXIDANT ACTIVITY; POLYPHENOLS; SERIES; CELLS; DERIVATIVES; FRACTIONS; POWER; BARK;

D O I：

10.1016/j.tet.2011.02.069

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学];

摘要：

A new stable organic free radical of the PTM (perchlorotriphenylmethyl) series very soluble in water is reported. This free radical is sensitive to electron transfer processes, and the selectivity of these reactions in the presence of ascorbic acid, pyrogallol, and catechol as reducing species is described. The electron paramagnetic resonance spectrum and the electrochemical behavior are also presented. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：3119 / 3123

页数：5

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