Saturated versus unsaturated: Ligand addition to the saturated metal site in an unsaturated binuclear metal complex

被引：6

作者：

Adams, Richard D. ^{[1
]}

Captain, Burjor ^{[1
]}

机构：

[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 30期

关键词：

ligand addition; phosphorus; rhenium; structure elucidation;

D O I：

10.1002/anie.200701370

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Pretty vacant: The unsymmetrical complex 1 contains one saturated 18-electron rhenium atom and one unsaturated 16-electron rhenium atom with a vacant coordination site. CO and NCMe can add to 1 to yield complexes in which both metal atoms have 18-electron configurations. Surprisingly, the added ligands are coordinated to the metal atom in 1 that originally had the 18-electron configuration. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5714 / 5716

页数：3

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