Calcium amidotrihydroborate: A hydrogen storage material

被引：208

作者：

Diyabalanage, Himashime V. K. ^{[1
]}

Shrestha, Roshan P. ^{[1
]}

Semelsberger, Troy A. ^{[1
]}

Scott, Brian L. ^{[1
]}

Bowden, Mark E. ^{[1
]}

Davis, Benjamin L. ^{[1
]}

Burrell, Anthony K. ^{[1
]}

机构：

[1] Los Alamos Natl Lab, Mat Phys & Applicat Div, Los Alamos, NM 87545 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 47期

关键词：

ammonia-borane; calcium; gas chromatography; hydrogen storage; thermal gravimetric analysis;

D O I：

10.1002/anie.200702240

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) No foaming at the mouth here: A calcium (II) derivative of ammonia-borane, Ca(NH2BH3)2 (see picture; green Ca, red O, blue N, yellow B, gray C, small green H), has thermal properties that are quite different from those of ammonia-borane. Ca(NH 2BH3)2 releases hydrogen over a temperature range of 100 to 170°C without foaming. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8995 / 8997

页数：3

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