Synthesis and characterization of a new three-dimensional aluminophosphate [Al11P12O48][C4H12N2][C4H11N2] with an Al/P ratio of 11:12

被引：24

作者：

Wang, KX ^{[1
]}

Yu, JH ^{[1
]}

Shi, Z ^{[1
]}

Miao, P ^{[1
]}

Yan, WF ^{[1
]}

Xu, RR ^{[1
]}

机构：

[1] Jilin Univ, Dept Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 12期

关键词：

D O I：

10.1039/b102327f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Employing piperazine as a template, a new three-dimensional aluminophosphate [Al11P12O48][C4H12N2][C4H11N2] (denoted AlPO-CJ11) has been prepared hydrothermally. The as-synthesized product has been characterized by X-ray powder diffraction, inductively coupled plasma, thermogravimetric and differential thermal analyses. Single crystal X-ray diffraction analysis shows that AlPO-CJ11 crystallizes in the trigonal space group R(3) over barc (no. 167) with a = 14.045(2) Angstrom, c = 42.091(6) Angstrom, V = 7191.0(16) Angstrom (3), and Z = 6. The framework structure of AlPO-CJ11 is constructed from two new types of chiral cage and has a new stoichiometry with an Al/P ratio of 11 : 12. The possible locations of the templates in the cages have been investigated by molecular modeling.

引用

页码：1809 / 1812

页数：4

共 32 条

[1]

[Anonymous], ANGEW CHEM

[2] THE PORE-SIZE MODIFICATION OF A LAYERED ALUMINOPHOSPHATE [AL3P4O16C9H24N3] BY RATIONAL SELECTION OF THE INTERCALATED TEMPLATE CATION [J].

BARRETT, PA ;

JONES, RH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (19) :1979-1981

[3]

CHIPPINDALE M, 1997, J CHEM SOC DA, P2639

[4]

Devosburchart E., 1992, Studies on Zeolites: Molecular Mechanics, Framework Stability, and Crystal growth

[5]

GAO Q, 1997, J SOLID STATE CHEM, V129, P3

[6] Transition-metal ions in aluminophosphate and silicoaluminophosphate molecular sieves: Location, interaction with adsorbates and catalytic properties [J].

Hartmann, M ;

Kevan, L .

CHEMICAL REVIEWS, 1999, 99 (03) :635-663

[7] SYNTHESIS AND CHARACTERIZATION OF A NOVEL EXTRA LARGE RING OF ALUMINOPHOSPHATE JDF-20 [J].

HUO, QH ;

XU, RR ;

LI, SG ;

MA, ZG ;

THOMAS, JM ;

JONES, RH ;

CHIPPINDALE, AM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (12) :875-876

[8] SYNTHESIS AND STRUCTURE OF A NOVEL ALUMINUM PHOSPHATE ANION - (AL3P4O16)3- [J].

JONES, RH ;

THOMAS, JM ;

XU, RR ;

HUO, QS ;

CHEETHAM, AK ;

POWELL, AV .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (18) :1266-1268

[9] A REACTIVE TEMPLATE IN THE SYNTHESIS OF A NOVEL LAYERED ALUMINUM PHOSPHATE (AL(3)P(4)O(16))(3-)[NH3(CH2)(5)NH3](2+)(C5H10NH2)+ [J].

JONES, RH ;

CHIPPINDALE, AM ;

NATARAJAN, S ;

THOMAS, JM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (05) :565-566

[10] Ambient-temperature synthesis of new layered AlPOs and GaPOs in silica gels [J].

Leech, MA ;

Cowley, AR ;

Prout, K ;

Chippindale, AM .

CHEMISTRY OF MATERIALS, 1998, 10 (01) :451-456

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