Synthesis and characterization of a new three-dimensional aluminophosphate [Al11P12O48][C4H12N2][C4H11N2] with an Al/P ratio of 11:12

被引：24

作者：

Wang, KX ^{[1
]}

Yu, JH ^{[1
]}

Shi, Z ^{[1
]}

Miao, P ^{[1
]}

Yan, WF ^{[1
]}

Xu, RR ^{[1
]}

机构：

[1] Jilin Univ, Dept Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 12期

关键词：

D O I：

10.1039/b102327f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Employing piperazine as a template, a new three-dimensional aluminophosphate [Al11P12O48][C4H12N2][C4H11N2] (denoted AlPO-CJ11) has been prepared hydrothermally. The as-synthesized product has been characterized by X-ray powder diffraction, inductively coupled plasma, thermogravimetric and differential thermal analyses. Single crystal X-ray diffraction analysis shows that AlPO-CJ11 crystallizes in the trigonal space group R(3) over barc (no. 167) with a = 14.045(2) Angstrom, c = 42.091(6) Angstrom, V = 7191.0(16) Angstrom (3), and Z = 6. The framework structure of AlPO-CJ11 is constructed from two new types of chiral cage and has a new stoichiometry with an Al/P ratio of 11 : 12. The possible locations of the templates in the cages have been investigated by molecular modeling.

引用

收藏

页码：1809 / 1812

页数：4

相关论文

共 32 条

[21] Synthesis and structure of Mu-4, the new layered aluminophosphate [(C2H5)2NH2]4[Al8P10O40H2]•[H2O]2.5 [J].

Vidal, L ;

Gramlich, V ;

Patarin, J ;

Gabelica, Z .

EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY, 1998, 35 (8-9) :545-563

[22] Solvothermal synthesis and characterization of a new 3-D open framework aluminophosphate [Al2P3O12][C4N3H16] [J].

Wei, B ;

Zhu, GS ;

Yu, JH ;

Qiu, SL ;

Xiao, FS ;

Terasaki, O .

CHEMISTRY OF MATERIALS, 1999, 11 (12) :3417-+

[23] Iridium(III) amine complexes as high-stability structure-directing agents for the synthesis of metal phosphates [J].

Williams, DJ ;

Kruger, JS ;

McLeroy, AF ;

Wilkinson, AP ;

Hanson, JC .

CHEMISTRY OF MATERIALS, 1999, 11 (08) :2241-2249

[24] Organo-template control of inorganic structures: A low-symmetry two-dimensional sheet aluminophosphate3[NH(3)CHMeCH(2)NH(3)][Al6P8O32]center dot H2O [J].

Williams, ID ;

Gao, QM ;

Chen, JS ;

Ngai, LY ;

Lin, ZY ;

Xu, RR .

CHEMICAL COMMUNICATIONS, 1996, (15) :1781-1782

[25] ALUMINOPHOSPHATE MOLECULAR-SIEVES - A NEW CLASS OF MICROPOROUS CRYSTALLINE INORGANIC SOLIDS [J].

WILSON, ST ;

LOK, BM ;

MESSINA, CA ;

CANNAN, TR ;

FLANIGEN, EM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (04) :1146-1147

[26] An open framework aluminophosphate with unique 12-membered ring channels:: Al9(PO4)12(C24H91N16) • 17H2O [J].

Xu, YH ;

Zhang, BG ;

Chen, XF ;

Liu, SH ;

Duan, CY ;

You, XZ .

JOURNAL OF SOLID STATE CHEMISTRY, 1999, 145 (01) :220-226

[27] [Al12P13O52]3-[(CH2)6N4H3]3+:: An anionic aluminophosphate molecular sieve with Bronsted acidity [J].

Yan, WF ;

Yu, JH ;

Xu, RR ;

Zhu, GS ;

Xiao, FS ;

Han, Y ;

Sugiyama, K ;

Terasaki, O .

CHEMISTRY OF MATERIALS, 2000, 12 (09) :2517-2519

[28] Synthesis and characterization of a new two-dimensional aluminophosphate layer and structural diversity in anionic aluminophosphates with Al2P3O123- stoichiometry [J].

Yu, J ;

Sugiyama, K ;

Hiraga, K ;

Togashi, N ;

Terasaki, O ;

Tanaka, Y ;

Nakata, S ;

Qiu, S ;

Xu, R .

CHEMISTRY OF MATERIALS, 1998, 10 (11) :3636-3642

[29] Al16P20O80H4.4C6H18N2:: A new microporous aluminophosphate containing intersecting 12- and 8-membered ring channels [J].

Yu, J ;

Sugiyama, K ;

Zheng, S ;

Qiu, S ;

Chen, J ;

Xu, R ;

Sakamoto, Y ;

Terasaki, O ;

Hiraga, K ;

Light, M ;

Hursthouse, MB ;

Thomas, JM .

CHEMISTRY OF MATERIALS, 1998, 10 (05) :1208-1211

[30] Formation of a new layered aluminophosphate [Al3P4O16][C5N2H9]2[NH4] [J].

Yu, J ;

Li, J ;

Sugiyama, K ;

Togashi, N ;

Terasaki, O ;

Hiraga, K ;

Zhou, B ;

Qiu, S ;

Xu, R .

CHEMISTRY OF MATERIALS, 1999, 11 (07) :1727-1732

← 1 2 3 4 →