Promotional effect of H2O on the activity of In2O3-doped Ga2O3-Al2O3 for the selective reduction of nitrogen monoxide

被引：36

作者：

Haneda, M ^{[1
]}

Kintaichi, Y ^{[1
]}

Hamada, H ^{[1
]}

机构：

[1] Natl Inst Mat & Chem Res, Tsukuba, Ibaraki 3058565, Japan

来源：

CATALYSIS LETTERS | 1998年 / 55卷 / 01期

关键词：

nitrogen monoxide; selective reduction; H2O; In2O3-Ga2O3-Al2O3; sol-gel method;

D O I：

10.1023/A:1019002105560

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Effect of metal oxide additives on the catalytic performance of Ga2O3-Al2O3 prepared by the sol-gel method for the selective reduction of NO with propene in the presence of oxygen was studied. Of several metal oxide additives, the addition of In2O3 enhanced drastically the activity of Ga2O3-Al2O3 for NO reduction by propene in the presence of H2O. In addition, the activity of In2O3-doped Ga2O3-Al2O3 catalyst was extremely intensified by the presence of H2O below 350 degrees C. The promotional effect of H2O was interpreted by the suppression of undesirable propene oxidation and the removal of carbonaceous materials deposited on the catalyst surface. We also found that close interaction of In2O3 and Ga2O3 is necessary for the enhancement of activity by H2O. A lot of hydrocarbons except methane and oxygenated compounds served as good reducing agents, among which propene and 2-propanol were the most efficient ones. In2O3-doped Ga2O3-Al2O3 catalyst was capable of reducing NO into N-2 quite efficiently in the presence of H2O at a very high space velocity.

引用

页码：47 / 55

页数：9

共 19 条

[11] Reduction of nitrogen oxides with hydrocarbons catalyzed by bifunctional catalysts [J].

Misono, M ;

Hirao, Y ;

Yokoyama, C .

CATALYSIS TODAY, 1997, 38 (02) :157-162

[12] Mechanism of reduction of nitrogen oxides with propene in excess oxygen catalyzed by bifunctional catalysts [J].

Misono, M ;

Niiro, H ;

Hirao, Y .

RESEARCH ON CHEMICAL INTERMEDIATES, 1998, 24 (02) :123-132

[13] ALUMINA-SUPPORTED CATALYSTS FOR THE SELECTIVE REDUCTION OF NITRIC-OXIDE BY PROPENE [J].

MIYADERA, T ;

YOSHIDA, K .

CHEMISTRY LETTERS, 1993, (09) :1483-1486

[14]

MIYADERA T, 1994, ADV MAT 93 A, V6, P405

[15] SELECTIVE REDUCTION OF NITRIC-OXIDE OVER CU-ZSM-5 ZEOLITE BY WATER-SOLUBLE OXYGEN-CONTAINING ORGANIC-COMPOUNDS [J].

MONTREUIL, CN ;

SHELEF, M .

APPLIED CATALYSIS B-ENVIRONMENTAL, 1992, 1 (01) :L1-L8

[16] Catalytic performance of silver ion-exchanged saponite for the selective reduction of nitrogen monoxide in the presence of excess oxygen [J].

Sato, K ;

Fujimoto, T ;

Kanai, S ;

Kintaichi, Y ;

Inaba, M ;

Haneda, M ;

Hamada, H .

APPLIED CATALYSIS B-ENVIRONMENTAL, 1997, 13 (01) :27-33

[17] SELECTIVE CATALYTIC REDUCTION OF NOX WITH N-FREE REDUCTANTS [J].

SHELEF, M .

CHEMICAL REVIEWS, 1995, 95 (01) :209-225

[18] Reduction of nitrogen monoxide with propene in the presence of oxygen and moisture over gold supported on metal oxides [J].

Ueda, A ;

Oshima, T ;

Haruta, M .

APPLIED CATALYSIS B-ENVIRONMENTAL, 1997, 12 (2-3) :81-93

[19] CATALYTIC REDUCTION OF NITROGEN-OXIDES BY PROPENE IN THE PRESENCE OF OXYGEN OVER CERIUM ION-EXCHANGED ZEOLITES .2. MECHANISTIC STUDY OF ROLES OF OXYGEN AND DOPED METALS [J].

YOKOYAMA, C ;

MISONO, M .

JOURNAL OF CATALYSIS, 1994, 150 (01) :9-17

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