Highly anisotropic opto-electronic properties of aligned films of self-assembled platinum molecular wires

被引：13

作者：

Debije, MG

de Haas, MP

Savenije, TJ

Warman, JM

Fontana, M

Stutzmann, N

Caseri, WR

Smith, P

机构：

[1] Radiation Chemistry Department, IRI, Delft University of Technology, NL-2629 JB Delft

[2] Department of Materials, Eidgenossische Tech. Hochsch. (ETH), CH-8092 Zürich

来源：

ADVANCED MATERIALS | 2003年 / 15卷 / 11期

关键词：

D O I：

10.1002/adma.200304603

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembled columns of alternating tetrachloro- and tetraalkylaminoplatinum moieties form stable, highly oriented, optically anisotropic films on a friction-deposited polytetrafluoroethylene surface (see Figure). Charge transport in the films is rapid (mobility greater than or equal to ca. 10(-2) cm(2) V-1 s(-)1) and highly one-dimensional along the axis of the columns (anisotropy greater than or equal to20), further substaining the potential application of these materials in molecular opto-electronic devices.

引用

页码：896 / +

页数：5

共 8 条

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