(Hot-)Water-Proof, semiconducting, platinum-based chain structures: Processing, products, and properties

被引：72

作者：

Caseri, WR

Chanzy, HD

Feldman, K

Fontana, M

Smith, P

Tervoort, TA

Goossens, JGP

Meijer, EW

Schenning, APHJ

Dolbnya, IR

Debije, MG

de Haas, MP

Warman, JM

van de Craats, AM

Friend, RH

Sirringhaus, H

Stutzmann, N

机构：

[1] Swiss Fed Inst Technol, Dept Mat, CH-8092 Zurich, Switzerland

[2] CNRS, Ctr Rech Macromol Vegetales, F-38041 Grenoble 9, France

[3] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands

[4] Eindhoven Univ Technol, Lab Polymer Technol, NL-5600 MB Eindhoven, Netherlands

[5] Netherlands Org Sci Res, NWO, ESRF, DUBBLE, F-38043 Grenoble, France

[6] Delft Univ Technol, Radiat Chem Dept, NL-2629 JB Delft, Netherlands

[7] Univ Cambridge, Cavendish Lab, Cambridge CB3 0HE, England

来源：

ADVANCED MATERIALS | 2003年 / 15卷 / 02期

关键词：

D O I：

10.1002/adma.200390024

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A promising solution to the environmental instability of semiconducting organic materials is presented. Thin, highly ordered films (see Figure, a scanning probe microscopy image), fibers, and field-effect transistors (FETs), comprising chain-structures based on the so-called Magnus' green salt, [Pt(NH3)(4)]-[PtCl4], were synthesized in aqueous media (see Cover). FETs were manufactured under ambient conditions from common organic solvents, and exposed-without significant loss of performance-to white light and air for periods of time in excess of 6 months, and to water of 90degreesC for more than 12 h.

引用

页码：125 / +

页数：6

共 33 条

[1] A new compound derived from Magnus' green salt: solid state structure and evidence for platinum chains in solution [J].