Stability, thermal homolysis and intermediate phases of solid hydroazafullerene C59HN

被引：8

作者：

Arcon, Denis

Pregelj, Matej

Cevc, Pavel

Rotas, Georgios

Pagona, Georgia

Tagmatarchis, Nikos

Ewels, Chris

机构：

[1] Univ Ljubljana, Jozef Stefan Inst, Ljubljana 1000, Slovenia

[2] Univ Ljubljana, Fac Math & Phys, Ljubljana, Slovenia

[3] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece

[4] Univ Nantes, CNRS, UMR6502, Inst Mat Jean Rouxel, F-44322 Nantes, France

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 32期

关键词：

D O I：

10.1039/b703766j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Density functional (DFT) calculations, high-temperature electron paramagnetic resonance (EPR) and transmission electron microscopy (TEM) results suggest that thermal homolysis of C59HN involves a remarkably stable intermediate C59N-C59HN center dot structure characterised by charge redistribution from a C59N center dot radical to a bonded C59HN.

引用

页码：3386 / 3388

页数：3

共 18 条

[1] THE UNUSUAL ELECTRON-SPIN-RESONANCE OF FULLERENE C60.- [J].

ALLEMAND, PM ;

SRDANOV, G ;

KOCH, A ;

KHEMANI, K ;

WUDL, F ;

RUBIN, Y ;

DIEDERICH, F ;

ALVAREZ, MM ;

ANZ, SJ ;

WHETTEN, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (07) :2780-2781

[2] IMPURITY STATES IN DOPED FULLERENES - C59B AND C59N [J].

ANDREONI, W ;

GYGI, F ;

PARRINELLO, M .

CHEMICAL PHYSICS LETTERS, 1992, 190 (3-4) :159-162

[3] Unconventional bonding of azafullerenes: Theory and experiment [J].

Andreoni, W ;

Curioni, A ;

Holczer, K ;

Prassides, K ;

KeshavarzK, M ;

Hummelen, JC ;

Wudl, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (45) :11335-11336

[4]

Briddon PR, 2000, PHYS STATUS SOLIDI B, V217, P131, DOI 10.1002/(SICI)1521-3951(200001)217:1<131::AID-PSSB131>3.0.CO

[5]

2-M

[6] On the crystal structure of azafullerene (C59N)(2) [J].

Brown, CM ;

Cristofolini, L ;

Kordatos, K ;

Prassides, K ;

Bellavia, C ;

Gonzalez, R ;

KeshavarzK, M ;

Wudl, F ;

Cheetham, AK ;

Zhang, JP ;

Andreoni, W ;

Curioni, A ;

Fitch, AN ;

Pattison, P .

CHEMISTRY OF MATERIALS, 1996, 8 (11) :2548-&

[7] Nitrogen violation of the isolated pentagon rule [J].

Ewels, Christopher P. .

NANO LETTERS, 2006, 6 (05) :890-895

[8] Azafullerene C59N, a stable free radical substituent in crystalline C60 [J].

Fülöp, F ;

Rockenbauer, A ;

Simon, F ;

Pekker, S ;

Korecz, L ;

Garaj, S ;

Jánossy, A .

CHEMICAL PHYSICS LETTERS, 2001, 334 (4-6) :233-237

[9] Photolysis of (C59N)(2) studied by time-resolved EPR [J].

Gruss, A ;

Dinse, KP ;

Hirsch, A ;

Nuber, B ;

Reuther, U .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (37) :8728-8729

[10] Light-induced ESR studies of the heterofullerene dimers [J].

Hasharoni, K ;

BellaviaLund, C ;

KeshavarzK, M ;

Srdanov, G ;

Wudl, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (45) :11128-11129

← 1 2 →