New molecular conductors containing magnetic tetrahedral anion, (DIETS)(2)FeX(4) and (DIETS)FeX(4): [DIETS equals diiodo-ethylenedithiodithiadiselenafulvalene, X=Cl,Br]

被引：8

作者：

Imakubo, T

Sawa, H

Kato, R

机构：

[1] Institute for Solid State Physics, University of Tokyo, Roppongi, Minato-ku

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1996年 / 285卷

基金：

日本学术振兴会;

关键词：

D O I：

10.1080/10587259608030774

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the crystals of new molecular conductors constructed by the Iodine-bonded pi-donor DIETS (diiodo-ethylenedithiodithiadiselenafulvalene) and magnetic anions FeX(4)(-) [X = Cl, Br] with tetrahedral symmetry, the unique -I ... X-cation ... anion interactions provide a variety of crystal structures.

引用

收藏

页码：27 / 32

页数：6

相关论文

共 9 条

[1] ASSEMBLY OF PORPHYRIN BUILDING-BLOCKS INTO NETWORK STRUCTURES WITH LARGE CHANNELS [J].

ABRAHAMS, BF ;

HOSKINS, BF ;

MICHAIL, DM ;

ROBSON, R .

NATURE, 1994, 369 (6483) :727-729

[2]

Desiraju G. R., 1989, DESIGN ORGANIC SOLID

[3] CYANO-HALOGEN INTERACTIONS AND THEIR ROLE IN THE CRYSTAL-STRUCTURES OF THE 4-HALOBENZONITRILES [J].

DESIRAJU, GR ;

HARLOW, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (17) :6757-6764

[4] NOVEL MOLECULAR CONDUCTORS, (DIETS)(4)M(CN)(4) (M=NI, PT) - HIGHLY RETICULATED DONOR-CENTER-DOT-CENTER-DOT-CENTER-DOT-ANION CONTACTS BY -I-CENTER-DOT-CENTER-DOT-CENTER-DOT-NC- INTERACTION [J].

IMAKUBO, T ;

SAWA, H ;

KATO, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (16) :1667-1668

[5] NOVEL RADICAL-CATION SALTS OF ORGANIC PI-DONORS CONTAINING IODINE ATOM(S) - THE FIRST APPLICATION OF STRONG INTERMOLECULAR -I-X- (X=CN, HALOGEN ATOM) INTERACTION TO MOLECULAR CONDUCTORS [J].

IMAKUBO, T ;

SAWA, H ;

KATO, R .

SYNTHETIC METALS, 1995, 73 (02) :117-122

[6] SYNTHESIS AND CRYSTAL-STRUCTURE OF THE MOLECULAR-METAL BASED ON IODINE-BONDED PI-DONOR, (IEDT)[PD(DMIT)(2)] [J].

IMAKUBO, T ;

SAWA, H ;

KATO, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (11) :1097-1098

[7] SUPERCONDUCTING AND SEMICONDUCTING MAGNETIC CHARGE-TRANSFER SALTS - (BEDT-TTF)(4)AFE(C(2)O4)(3)CENTER-DOT-C6H5CN (A=H2O, K, NH4) [J].

KURMOO, M ;

GRAHAM, AW ;

DAY, P ;

COLES, SJ ;

HURSTHOUSE, MB ;

CAULFIELD, JL ;

SINGLETON, J ;

PRATT, FL ;

HAYES, W ;

DUCASSE, L ;

GUIONNEAU, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (49) :12209-12217

[8] CRYSTAL-STRUCTURES AND PHYSICAL-PROPERTIES OF BIS(ETHYLENEDITHIO)-TETRATHIAFULVALENE CHARGE-TRANSFER SALTS WITH FECL4-ANIONS OR FEBR4-ANIONS [J].

MALLAH, T ;

HOLLIS, C ;

BOTT, S ;

KURMOO, M ;

DAY, P ;

ALLAN, M ;

FRIEND, RH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (03) :859-865

[9] CRYSTAL STRUCTURE OF P-IODOBENZONITRILE [J].

SCHLEMPE.EO ;

BRITTON, D .

ACTA CRYSTALLOGRAPHICA, 1965, 18 :419-&