Regioselectivity, stereoselectivity and catalysis in intermolecular Pauson-Khand reactions: Teaching an old dog new tricks

被引：139

作者：

Laschat, S ^{[1
]}

Becheanu, A ^{[1
]}

Bell, T ^{[1
]}

Baro, A ^{[1
]}

机构：

[1] Univ Stuttgart, Inst Organ Chem, D-70569 Stuttgart, Germany

来源：

SYNLETT | 2005年 / 17期

关键词：

Pauson-Khand reaction; metal-catalysis; stereoselectivity; theoretical studies;

D O I：

10.1055/s-2005-918922

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Since its discovery in the early seventies the intermolecular Pauson-Khand reaction has made considerable progress towards a powerful synthetic method. This account describes the major accomplishments with respect to reactivity, stereoselectivity and catalytic versions, which have been achieved over the last decade and summarizes mechanistic information being obtained by theoretical and experimental studies.

引用

页码：2547 / 2570

页数：24

共 197 条

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