Tunable Luminescence of Sr2CeO4:M2+ (M = Ca, Mg, Ba, Zn) and Sr2CeO4:Ln3+ (Ln = Eu, Dy, Tm) Nanophosphors

被引：83

作者：

Grzyb, Tomasz ^{[1
]}

Szczeszak, Agata ^{[1
]}

Rozowska, Justyna ^{[1
]}

Legendziewicz, Janina ^{[2
]}

Lis, Stefan ^{[1
]}

机构：

[1] Adam Mickiewicz Univ, Fac Chem, Dept Rare Earths, PL-60780 Poznan, Poland

[2] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2012年 / 116卷 / 05期

关键词：

SPECTROSCOPIC PROPERTIES; PHOSPHOR; PHOTOLUMINESCENCE; PARTICLES; EMISSION;

D O I：

10.1021/jp208015z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nanophosphors based on cerium-strontium oxide (Sr2CeO4), doped with M2+ or Ln(3+) (M = Ca, Mg, Ba, Zn; Ln = Eu, Dy, Tm) were successfully prepared using a modified Pechini method. The structure of prepared materials has been confirmed and characterized using several techniques such as X-ray powder diffraction (XRD), scanning and transmission electron microscopy (SEM and TEM). The obtained materials were composed of nanocrystals with an average size around similar to 50 nm. The luminescence properties of synthesized nanophosphors were characterized by excitation or emission spectra and luminescence lifetimes. The chromaticity coordinates were also calculated to demonstrate changes of the luminescence color.

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页码：3219 / 3226

页数：8

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