Lanthanide-Based Luminescent Hybrid Materials

被引:3014
作者
Binnemans, Koen [1 ]
机构
[1] Katholieke Univ Leuven, Dept Chem, B-3001 Louvain, Belgium
关键词
RARE-EARTH-METAL; SOL-GEL SILICA; INTRAMOLECULAR ENERGY-TRANSFER; ORGANIC ELECTROLUMINESCENT DEVICES; NEAR-INFRARED-LUMINESCENCE; SURFACTANT-ENCAPSULATED POLYOXOMETALATE; LANGMUIR-BLODGETT-FILMS; IN-SITU SYNTHESIS; LAYERED DOUBLE HYDROXIDES; MOLECULAR-BASED HYBRIDS;
D O I
10.1021/cr8003983
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The different types of lanthanide based hybrid materials and their advantages and disadvantages have been demonstrated. These hybrid materials have superior mechanical properties and have a better processability than the pure molecular lanthanide complexes and embedding a lanthanide complex in a hybrid matrix is also beneficial for its thermal stability and luminescence output. The first lanthanide doped sol-gel silica glasses samples were prepared by dissolving inorganic lanthanide salts like hydrated europium, chloride or europium nitrate in the solution. The incorporation of a lanthanide complex into an inorganic hybrid matrix significantly improves its thermal and (photo) chemical stability. The lanthanide-doped nanoparticle offers an alternative for the lanthanide β-dike-tonates.
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页码:4283 / 4374
页数:92
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