Analysis of organometallic compounds using ion trap mass spectrometry

被引：90

作者：

Dyson, PJ ^{[1
]}

McIndoe, JS

机构：

[1] Ecole Polytech Fed Lausanne, Inst Chim Mol & Biol, BCH, CH-1015 Lausanne, Switzerland

[2] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

INORGANICA CHIMICA ACTA | 2003年 / 354卷

关键词：

mass spectrometry; electrospray ionisation; ion trap; organometallic compounds; clusters; ionic clusters;

D O I：

10.1016/S0020-1693(03)00369-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ion traps are an increasingly common presence as mass analysers in commercial bench-top mass spectrometers. Such instruments, usually interfaced with electrospray ionisation or nanospray sources, are invariably aimed at organic and biological applications, such as in the analysis of proteins, pharmaceuticals, organics, biomarkers, metabolites, etc. However, the abilities of ion trap mass spectrometers (extraordinary sensitivity, good resolution, MS" for structural information) can be profitably employed in the analysis of inorganic and organometallic compounds. We highlight these abilities, identify various problems and suggest the areas that will perhaps benefit most from employment of ion trap instruments. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：68 / 74

页数：7

共 39 条

[11] Direct analysis of catalysts immobilised in ionic liquids using electrospray ionisation ion trap mass spectrometry [J].

Dyson, PJ ;

McIndoe, JS ;

Zhao, DB .

CHEMICAL COMMUNICATIONS, 2003, (04) :508-509

[12] Minor modifications to the ligands surrounding a ruthenium complex lead to major differences in the way in which they catalyse the hydrogenation of arenes [J].

Dyson, PJ ;

Ellis, DJ ;

Laurenczy, G .

ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (1-2) :211-215

[13] Laser desorption ionization versus electrospray ionization mass spectrometry:: Applications in the analysis of cluster anions [J].

Dyson, PJ ;

Hearley, AK ;

Johnson, BFG ;

McIndoe, JS ;

Langridge-Smith, PRR .

JOURNAL OF CLUSTER SCIENCE, 2001, 12 (01) :273-283

[14] Combining energy-dependent electrospray ionisation with tandem mass spectrometry for the analysis of inorganic compounds [J].

Dyson, PJ ;

Hearley, AK ;

Johnson, BFG ;

McIndoe, JS ;

Langridge-Smith, PRR ;

Whyte, C .

RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2001, 15 (12) :895-897

[15] Mass spectrometric method for the rapid characterization of transition metal carbonyl cluster reaction mixtures [J].

Dyson, PJ ;

Hearley, AK ;

Johnson, BFG ;

Khimyak, T ;

McIndoe, JS ;

Langridge-Smith, PRR .

ORGANOMETALLICS, 2001, 20 (19) :3970-3974

[16]

Dyson PJ, 2000, RAPID COMMUN MASS SP, V14, P311, DOI 10.1002/(SICI)1097-0231(20000315)14:5<311::AID-RCM824>3.0.CO

[17]

2-H

[18] Applications of laser desorption and electrospray ionization mass spectrometry at the transition between clusters and colloids [J].

Dyson, PJ ;

Johnson, BFG ;

McIndoe, JS ;

Langridge-Smith, PRR .

INORGANIC CHEMISTRY, 2000, 39 (12) :2430-+

[19] THE SYNTHESIS AND CHARACTERIZATION OF SOME MIXED-METAL CARBONYL HYDRIDES CONTAINING TUNGSTEN - THE X-RAY CRYSTAL-STRUCTURE OF [(PH3P)2N]OS3WH(CO)14] [J].

FAJARDO, M ;

GOMEZSAL, MP ;

JOHNSON, BFG ;

LEWIS, J ;

RAITHBY, PR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 272 (03) :C57-C61

[20] ELECTROSPRAY IONIZATION-PRINCIPLES AND PRACTICE [J].

FENN, JB ;

MANN, M ;

MENG, CK ;

WONG, SF ;

WHITEHOUSE, CM .

MASS SPECTROMETRY REVIEWS, 1990, 9 (01) :37-70

← 1 2 3 4 →