Stereoselective synthesis of ABC-ring system of hemibrevetoxin B

被引：24

作者：

Matsukura, H ^{[1
]}

Morimoto, M ^{[1
]}

Nakata, T ^{[1
]}

机构：

[1] RIKEN, INST PHYS & CHEM RES, WAKO, SAITAMA 35101, JAPAN

来源：

CHEMISTRY LETTERS | 1996年 / 06期

关键词：

D O I：

10.1246/cl.1996.487

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 6, 6, 7-membered tricyclic ether ring system (ABC-ring) of hemibrevetoxin B was stereoselectively synthesized. The crucial steps in the present synthesis involve the ring expansion of tetrahydropyran to oxepane, 6-endo cyclization of epoxy alcohol, and insertion of a C-4 unit to the A-ring.

引用

页码：487 / 488

页数：2

共 16 条

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