New P-chirogenic phosphine ligands and their use in catalytic asymmetric reactions

被引：146

作者：

Crépy, KVL ^{[1
]}

Imamoto, T ^{[1
]}

机构：

[1] Chiba Univ, Fac Sci, Dept Chem, Inage Ku, Chiba 2638522, Japan

来源：

NEW ASPECTS IN PHOSPHORUS CHEMISTRY III | 2003年 / 229卷

关键词：

P-chirogenic phosphine ligands; C-2-symmetry; phosphine-boranes; transition-metal catalysts; catalytic asymmetric reactions;

D O I：

10.1007/b11148

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This chapter is concerned with an update on the preparation and applications of optically active phosphine ligands which bear the chiral center at a phosphorus atom. A great deal of P-chirogenic ligands have been reported over the past ten years, and their unique structure reproduced here. However, only syntheses of ligands which have been the subject of several literature reports in terms of applications to asymmetric catalysis have been summarized. This review also aimed to introduce the latest results in the field of enantioselective reactions.

引用

页码：1 / 40

页数：40

共 139 条

[31] A PRACTICAL, HIGHLY ENANTIOSELECTIVE SYNTHESIS OF THE TAXOL SIDE-CHAIN VIA ASYMMETRIC CATALYSIS [J].

DENG, L ;

JACOBSEN, EN .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (15) :4320-4323

[32] Novel ferrocenyl ligands with planar and central chirality in Pd-catalyzed allylic substitutions [J].

Enders, D ;

Peters, R ;

Runsink, J ;

Bats, JW .

ORGANIC LETTERS, 1999, 1 (11) :1863-1866

[33] Application of chiral mixed phosphorus/sulfur ligands to palladium-catalyzed allylic substitutions [J].

Evans, DA ;

Campos, KR ;

Tedrow, JS ;

Michael, FE ;

Gagné, MR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (33) :7905-7920

[34] Highly enantioselective catalytic conjugate addition and tandem conjugate addition - Aldol reactions of organozinc reagents [J].

Feringa, BL ;

Pineschi, M ;

Arnold, LA ;

Imbos, R ;

de Vries, AHM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (23) :2620-2623

[35]

Fuhrhop J., 1994, ORGANIC SYNTHESIS

[36] Foldamers: A manifesto [J].

Gellman, SH .

ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (04) :173-180

[37] OXO COMPLEXES OF RUTHENIUM(VI) AND (VII) AS ORGANIC OXIDANTS [J].

GREEN, G ;

GRIFFITH, WP ;

HOLLINSHEAD, DM ;

LEY, SV ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1984, (04) :681-686

[38] On the origin of opposite stereoselection in the asymmetric hydrogenation of phenyl- and tert-butyl-substituted enamides [J].

Gridnev, ID ;

Higashi, N ;

Imamoto, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (42) :10486-10487

[39] Formation of a stable rhodium(I) dihydride complex and its reactions with prochiral substrates of asymmetric hydrogenation [J].

Gridnev, ID ;

Higashi, N ;

Imamoto, T .

ORGANOMETALLICS, 2001, 20 (22) :4542-4553

[40] Asymmetric hydrogenation of enamides with Rh-BisP* and Rh-MiniPHOS catalysts. Scope, limitations, and mechanism [J].

Gridnev, ID ;

Yasutake, M ;

Higashi, N ;

Imamoto, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (22) :5268-5276

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