Imprinting for the assembly of artificial receptors on a silica surface

被引：22

作者：

Hwang, KO ^{[1
]}

Sasaki, T ^{[1
]}

机构：

[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1998年 / 8卷 / 09期

关键词：

D O I：

10.1039/a801932k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Molecular imprinting of a solid surface provides a means to introduce reactive functionalities with a defined geometry on the surface. A silica surface was imprinted with a tridentate metal complex, Ru[bipy-CH=NCH2CH2CH2Si(OEt)(3)](3). The molecular imprinting process leaves three amino groups per Ru-II complex. The imprinted silica was reacted with various aldehydes to assemble artificial receptor sites on the surface. A metal binding site for Fe-II was constructed with a bipyridine-modified aldehyde that was selectively adsorbed on the surface in the presence of other two aldehydes and Fe-II.

引用

页码：2153 / 2156

页数：4

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