Highly enantioselective spiro cyclization of 1,6-enynes catalyzed by cationic skewphos rhodium(I) complex

被引：39

作者：

Mikami, K ^{[1
]}

Yusa, Y ^{[1
]}

Hatano, M ^{[1
]}

Wakabayashi, K ^{[1
]}

Aikawa, K ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Appl Chem, Tokyo 1528552, Japan

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 01期

关键词：

D O I：

10.1039/b310789b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cationic rhodium(I) complex having a skewphos ligand is shown to be a highly enantioselective catalyst for asymmetric carbocyclization of 1,6-enynes with tri-substituted olefins to control quaternary stereogenic centers of spiro-rings.

引用

页码：98 / 99

页数：2

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