Preparation of Hybrid Latex Particles and Core-Shell Particles Through the Use of Controlled Radical Polymerization Techniques in Aqueous Media

被引：57

作者：

Charleux, Bernadette ^{[1
]}

D'Agosto, Franck ^{[1
]}

Delaittre, Guillaume ^{[2
]}

机构：

[1] Univ Lyon 1, Lab Chim Catalyse Polymores & Procedes C2P2, CNRS UMR 5265, CPE Lyon, F-69616 Villeurbanne, France

[2] Radboud Univ Nijmegen, Inst Mol & Mat, NL-6525 ED Nijmegen, Netherlands

来源：

HYBRID LATEX PARTICLES: PREPARATION WITH (MINI) EMULSION POLYMERIZATION | 2010年 / 233卷

关键词：

Controlled/living radical polymerization; Core shell particle; Dispersion polymerization; Emulsion polymerization; Grafting from; Hybrid; Miniemulsion polymerization; Nanogel; Nanoparticle; INITIO EMULSION POLYMERIZATION; FRAGMENTATION CHAIN TRANSFER; WATER-SOLUBLE ALKOXYAMINE; N-BUTYL ACRYLATE; AMPHIPHILIC DIBLOCK COPOLYMER; TRANSFER RAFT POLYMERIZATION; BLOCK-COPOLYMER; IN-SITU; POLYSTYRENE-LATEX; DISPERSION POLYMERIZATION;

D O I：

10.1007/12_2010_64

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of hybrid and core shell nanoparticles using controlled/living radical polymerization in aqueous dispersed systems is reviewed. The processes involve emulsion, miniemulsion, and dispersion polymerizations as well as grafting techniques, with the aim of producing submicrometric latex particles with well-defined morphologies that might not be accessible via classical radical polymerization. Those morphologies include organic/inorganic hybrids, nanostructured particles, (nano)capsules, and particles with a hydrophobic core and hydrophilic shell.

引用

收藏

页码：125 / 183

页数：59

相关论文

共 172 条

[31] Surface polymerization of hydrophilic methacrylates from ultrafine silica sols in protic media at ambient temperature: A novel approach to surface functionalization using a polyelectrolytic macroinitiator [J].

Chen, XY ;

Armes, SP .

ADVANCED MATERIALS, 2003, 15 (18) :1558-+

[32] Growth of Lightly Crosslinked PHEMA Brushes and Capsule Formation Using Pickering Emulsion Interface-Initiated ATRP [J].

Chen, Yunhua ;

Wang, Chaoyang ;

Chen, Jianxin ;

Liu, Xinxing ;

Tong, Zhen .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (05) :1354-1367

[33] Organic/Inorganic hybrid nanospheres coated with Palladium/P4VP shells from surface-initiated atom transfer radical polymerization [J].

Cheng, Zhenping ;

Zhang, Lifen ;

Zhu, Xiulin ;

Kang, E. T. ;

Neoh, K. G. .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (06) :2119-2131

[34] Living free-radical polymerization by reversible addition-fragmentation chain transfer: The RAFT process [J].

Chiefari, J ;

Chong, YK ;

Ercole, F ;

Krstina, J ;

Jeffery, J ;

Le, TPT ;

Mayadunne, RTA ;

Meijs, GF ;

Moad, CL ;

Moad, G ;

Rizzardo, E ;

Thang, SH .

MACROMOLECULES, 1998, 31 (16) :5559-5562

[35] Thiocarbonylthio compounds (S=C(Z)S-R) in free radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization). Effect of the activating group Z [J].

Chiefari, J ;

Mayadunne, RTA ;

Moad, CL ;

Moad, G ;

Rizzardo, E ;

Postma, A ;

Skidmore, MA ;

Thang, SH .

MACROMOLECULES, 2003, 36 (07) :2273-2283

[36] Thiocarbonylthio compounds [S=C(Ph)S-R] in free radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization). Role of the free-radical leaving group (R) [J].

Chong, YK ;

Krstina, J ;

Le, TPT ;

Moad, G ;

Postma, A ;

Rizzardo, E ;

Thang, SH .

MACROMOLECULES, 2003, 36 (07) :2256-2272

[37] Synthesis of novel size exclusion chromatography support by surface initiated aqueous atom transfer radical polymerization [J].

Coad, Bryan R. ;

Kizhakkedathu, Jayachandran N. ;

Haynes, Charles A. ;

Brooks, Donald E. .

LANGMUIR, 2007, 23 (23) :11791-11803

[38] First nitroxide-mediated controlled free-radical polymerization of acrylic acid [J].

Couvreur, L ;

Lefay, C ;

Belleney, J ;

Charleux, B ;

Guerret, O ;

Magnet, S .

MACROMOLECULES, 2003, 36 (22) :8260-8267

[39] Living/controlled radical polymerizations in dispersed phase systems [J].

Cunningham, MF .

PROGRESS IN POLYMER SCIENCE, 2002, 27 (06) :1039-1067

[40] Controlled/living radical polymerization in aqueous dispersed systems [J].

Cunningham, Michael F. .

PROGRESS IN POLYMER SCIENCE, 2008, 33 (04) :365-398

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