Measurement of OH and HO2 in the troposphere

被引:330
作者
Heard, DE [1 ]
Pilling, MJ [1 ]
机构
[1] Univ Leeds, Dept Chem, Leeds LS2 9JT, W Yorkshire, England
关键词
D O I
10.1021/cr020522s
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The measurement of OH and HO2 in the troposphere was discussed. The detection limit, time response and accuracy of the methods used to measure tropospheric OH were studied. It was found that OH measurements were accompanied by ancilliary measurements of source and sink species. The field measurement of OH showed considerable variability on time scales of 10-30 s due to rapid changes in the parameters that control the rate of OH production and loss.
引用
收藏
页码:5163 / 5198
页数:36
相关论文
共 273 条
  • [1] Hydroxyl radical and ozone measurements in England during the solar eclipse of 11 August 1999
    Abram, JP
    Creasey, DJ
    Heard, DE
    Lee, JD
    Pilling, MJ
    [J]. GEOPHYSICAL RESEARCH LETTERS, 2000, 27 (21) : 3437 - 3440
  • [2] OH formation by HONO photolysis during the BERLIOZ experiment -: art. no. 8247
    Alicke, B
    Geyer, A
    Hofzumahaus, A
    Holland, F
    Konrad, S
    Pätz, HW
    Schäfer, J
    Stutz, J
    Volz-Thomas, A
    Platt, U
    [J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2003, 108 (D4)
  • [3] Experimental evidence for the existence of the HO2-H2O complex
    Aloisio, S
    Francisco, JS
    Friedl, RR
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (28) : 6597 - 6601
  • [4] Radical-water complexes in Earth's atmosphere
    Aloisio, S
    Francisco, JS
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (12) : 825 - 830
  • [5] Reactive quenching of electronically excited OH radicals in collisions with molecular hydrogen
    Anderson, DT
    Todd, MW
    Lester, MI
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (23) : 11117 - 11120
  • [6] HO-2 IN THE STRATOSPHERE - 3 INSITU OBSERVATIONS
    ANDERSON, JG
    GRASSL, HJ
    SHETTER, RE
    MARGITAN, JJ
    [J]. GEOPHYSICAL RESEARCH LETTERS, 1981, 8 (03) : 289 - 292
  • [7] ABSOLUTE CONCENTRATION OF OH(X2PI) IN EARTHS STRATOSPHERE
    ANDERSON, JG
    [J]. GEOPHYSICAL RESEARCH LETTERS, 1976, 3 (03) : 165 - 168
  • [8] OH MULTIPASS ABSORPTION - ABSOLUTE AND IN-SITU METHOD FOR LOCAL MONITORING OF TROPOSPHERIC HYDROXYL RADICALS
    ARMERDING, W
    SPIEKERMANN, M
    COMES, FJ
    [J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1994, 99 (D1) : 1225 - 1239
  • [9] ARMERDING W, 1995, J ATMOS SCI, V52, P3381, DOI 10.1175/1520-0469(1995)052<3381:MAALSF>2.0.CO
  • [10] 2