Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type:: structural and magnetic characterisations of [Cu7(OH)6Cl2(pn)6(H2O)2](C(CN)3)4Cl2 (pn=1,3-diaminopropane)

被引：37

作者：

Triki, S

Thétiot, F

Pala, JS

Golhen, S

Clemente-Juan, JM

Gómez-García, CJ

Coronado, E

机构：

[1] Univ Bretagne Occidentale, CNRS, UMR 6521, F-29285 Brest, France

[2] Univ Rennes 1, CNRS, UMR 6511, F-35042 Rennes, France

[3] Univ Valencia, Inst Ciencia Mol, E-46100 Burjassot, Spain

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 21期

关键词：

D O I：

10.1039/b105231b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new polynuclear copper(II) complex [Cu-7(OH)(6)Cl-2-(pn)(6)(H2O)(2)](C(CN)(3))(4)Cl-2 with hydroxo-bridging ligands has been prepared; the centrosymmetric cluster cation can be described as two Cu4O3Cl distorted cubane units sharing one copper cation.

引用

收藏

页码：2172 / 2173

页数：2

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