Polymorphism-dependent fluorescence of 9,10-bis(pentafluorobenzoyloxy)anthracene

被引:28
作者
Kohmoto, Shigeo [1 ]
Tsuyuki, Ryota [1 ]
Masu, Hyuma [2 ]
Azumaya, Isao [2 ]
Kishikawa, Keiki [1 ]
机构
[1] Chiba Univ, Grad Sch Engn, Dept Appl Chem & Biotechnol, Inage Ku, Chiba 263, Japan
[2] Tokushima Bunri Univ, Fac Pharmaceut Sci, Kagawa 7692193, Japan
基金
日本学术振兴会;
关键词
D O I
10.1016/j.tetlet.2007.11.024
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Anthracene derivatives possessing pentafluorobenzoyloxy moieties at 9- and 10-positions showed polymorphism affording two types of fluorescent crystals with blue and bluish green fluorescence in their crystalline state, respectively. Their single crystal X-ray structures showed that the degree of overlap of anthracene moieties was responsible for the difference in fluorescence. Fluorescence in the crystalline state originated in the dimer emission deduced from their excitation spectra. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:39 / 43
页数:5
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