Modeling Carbon Dioxide Adsorption on Microporous Substrates: Comparison between Cu-BTC Metal-Organic Framework and 13X Zeolitic Molecular Sieve

被引：119

作者：

Aprea, Paolo ^{[2
]}

Caputo, Domenico ^{[2
]}

Gargiulo, Nicola ^{[2
]}

Iucolano, Fabio ^{[2
]}

Pepe, Francesco ^{[1
]}

机构：

[1] Univ Sannio, Dipartimento Ingn, I-82100 Benevento, Italy

[2] Univ Naples Federico II, Dipartimento Ingn Mat & Prod, I-80125 Naples, Italy

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2010年 / 55卷 / 09期

关键词：

CO2; ADSORPTION; BASIC SITES; GAS; SEPARATION; STORAGE; SBA-15;

D O I：

10.1021/je1002225

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

In this work, CO2 adsorption on a laboratory-synthesized polymeric copper(II) benzene-1,3,5-tricarboxylate (Cu-BTC) metal-organic framework was modeled by means of the semiempirical Sips equation in order to obtain parameters of engineering interest. Produced Cu-BTC samples were characterized by X-ray diffraction, thermogravimetry, and microporosimetric analysis; high crystallinity and very high specific surface area and pore volume were found. CO2 adsorption isotherms on Cu-BTC were evaluated at T = (283, 293, 318, and 343) K for p <= 1 bar by means of a volumetric technique. In order to establish a comparison, CO2 adsorption isotherms on samples of commercial 13X zeolite were determined under the same experimental conditions and then modeled in the same way as those for Cu-BTC. The modeling and experimental results indicated that relative to 13X zeolite, Cu-BTC showed higher CO2 adsorption capacities at near-ambient temperature and a lower heat release during the adsorption phase.

引用

页码：3655 / 3661

页数：7

共 32 条

[1] [Anonymous], CLIM CHANG 2007 SYNT
[2] [Anonymous], 1998, ADSORPTION ANALYSISE
[3] Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47
Bourrelly, S
Llewellyn, PL
Serre, C
Millange, F
Loiseau, T
Férey, G
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (39) : 13519 - 13521
[4] Breck DW., 1974, Zeolite Molecular Sieves
[5] Chaffee AL, 2002, ABSTR PAP AM CHEM S, V223, pU572
[6] In-situ infrared study of CO2 adsorption on SBA-15 grafted with γ-(aminopropyl)triethoxysilane
Chang, ACC
Chuang, SSC
Gray, M
Soong, Y
[J]. ENERGY & FUELS, 2003, 17 (02) : 468 - 473
[7] Comparison of adsorption isotherms on Cu-BTC metal organic frameworks synthesized from different routes
Chowdhury, Pradip
Bikkina, Chaitanya
Meister, Dirk
Dreisbach, Frieder
Gumma, Sasidhar
[J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2009, 117 (1-2) : 406 - 413
[8] COMPARISON OF ACTIVATED CARBON AND ZEOLITE 13X FOR CO2 RECOVERY FROM FLUE-GAS BY PRESSURE SWING ADSORPTION
CHUE, KT
KIM, JN
YOO, YJ
CHO, SH
YANG, RT
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1995, 34 (02) : 591 - 598
[9] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n
Chui, SSY
Lo, SMF
Charmant, JPH
Orpen, AG
Williams, ID
[J]. SCIENCE, 1999, 283 (5405) : 1148 - 1150
[10] A chromium terephthalate-based solid with unusually large pore volumes and surface area
Férey, G
Mellot-Draznieks, C
Serre, C
Millange, F
Dutour, J
Surblé, S
Margiolaki, I
[J]. SCIENCE, 2005, 309 (5743) : 2040 - 2042

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