From Metal-Organic Framework to Nanoporous Carbon: Toward a Very High Surface Area and Hydrogen Uptake

被引：1093

作者：

Jiang, Hai-Long ^{[1
]}

Liu, Bo ^{[1
]}

Lan, Ya-Qian ^{[1
]}

Kuratani, Kentaro ^{[1
]}

Akita, Tomoki ^{[1
]}

Shioyama, Hiroshi ^{[1
]}

Zong, Fengqi ^{[2
]}

Xu, Qiang ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Osaka 5638577, Japan

[2] Changzhou Univ, Analyt & Testing Ctr, Changzhou, Jiangsu, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 31期

关键词：

TEMPLATED MESOPOROUS CARBONS; CARBIDE-DERIVED CARBONS; STORAGE CAPACITY; SEPARATION; POROSITY; ACID;

D O I：

10.1021/ja203184k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this work, with a zeolite-type metal organic framework as both a precursor and a template and furfuryl alcohol as a second precursor, nanoporous carbon material has been prepared with an unexpectedly high surface area (3405 m(2)/g, BET method) and considerable hydrogen storage capacity (2.77 wt % at 77 K and 1 atm) as well as good electrochemical properties as an electrode material for electric double layer capacitors. The pore structure and surface area of the resultant carbon materials can be tuned simply by changing the calcination temperature.

引用

页码：11854 / 11857

页数：4

共 64 条

[1] Evaluation of the BET Method for Determining Surface Areas of MOFs and Zeolites that Contain Ultra-Micropores [J].

Bae, Youn-Sang ;

Yazaydin, A. Oezguer ;

Snurr, Randall Q. .

LANGMUIR, 2010, 26 (08) :5475-5483

[2] Metal-Organic Frameworks with Functional Pores for Recognition of Small Molecules [J].

Chen, Banglin ;

Xiang, Shengchang ;

Qian, Guodong .

ACCOUNTS OF CHEMICAL RESEARCH, 2010, 43 (08) :1115-1124

[3] Nanochannels of two distinct cross-sections in a porous Al-based coordination polymer [J].

Comotti, Angiolina ;

Bracco, Silvia ;

Sozzani, Piero ;

Horike, Satoshi ;

Matsuda, Ryotaro ;

Chen, Jinxi ;

Takata, Masaki ;

Kubota, Yoshiki ;

Kitagawa, Susumu .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (41) :13664-13672

[4] Rational Design, Synthesis, Purification, and Activation of Metal-Organic Framework Materials [J].

Farha, Omar K. ;

Hupp, Joseph T. .

ACCOUNTS OF CHEMICAL RESEARCH, 2010, 43 (08) :1166-1175

[5] A chromium terephthalate-based solid with unusually large pore volumes and surface area [J].

Férey, G ;

Mellot-Draznieks, C ;

Serre, C ;

Millange, F ;

Dutour, J ;

Surblé, S ;

Margiolaki, I .

SCIENCE, 2005, 309 (5743) :2040-2042

[6] Carbon materials for lithium-ion rechargeable batteries [J].

Flandrois, S ;

Simon, B .

CARBON, 1999, 37 (02) :165-180

[7] Templated mesoporous carbons for supercapacitor application [J].

Fuertes, AB ;

Lota, G ;

Centeno, TA ;

Frackowiak, E .

ELECTROCHIMICA ACTA, 2005, 50 (14) :2799-2805

[8] Ultrahigh Porosity in Metal-Organic Frameworks [J].

Furukawa, Hiroyasu ;

Ko, Nakeun ;

Go, Yong Bok ;

Aratani, Naoki ;

Choi, Sang Beom ;

Choi, Eunwoo ;

Yazaydin, A. Oezguer ;

Snurr, Randall Q. ;

O'Keeffe, Michael ;

Kim, Jaheon ;

Yaghi, Omar M. .

SCIENCE, 2010, 329 (5990) :424-428

[9] Tailoring of nanoscale porosity in carbide-derived carbons for hydrogen storage [J].

Gogotsi, Y ;

Dash, RK ;

Yushin, G ;

Yildirim, T ;

Laudisio, G ;

Fischer, JE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (46) :16006-16007

[10] Controllability of pore characteristics of resorcinol-formaldehyde carbon aerogel [J].

Horikawa, T ;

Hayashi, J ;

Muroyama, K .

CARBON, 2004, 42 (8-9) :1625-1633

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