Metallaboratranes:: The m→B dative bond as a ligand activating function in the phosphaboration of carbon monosulfide

被引：66

作者：

Crossley, Ian R. ^{[1
]}

Hill, Anthony F. ^{[1
]}

Willis, Anthony C. ^{[1
]}

机构：

[1] Australian Natl Univ, Res Sch Chem, Inst Adv Studies, Canberra, ACT, Australia

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 16期

关键词：

D O I：

10.1021/om700433q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Na[H2B(mt)(2)] (mt = methimazolyl) with [RhCl(CO)(PPh3)(2)] proceeds via simple metathesis to provide the complex [Rh(CO)(PPh3){H2B(mt)(2)}]; however, with [RhCl(CS)(PPh3)(2)] C,C-phosphaboration of the thiocarbonyl ligand occurs, with formation of the novel cage complex [RhH(PPh3){eta(2)(C,S),kappa S-2',S ''-SC(PPh3)BH(mt)(2)}].

引用

页码：3891 / 3895

页数：5

共 59 条

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