Facile and selective alkylation of 3,3,3-trifluoropropene oxide (TFPO) with organoaluminum reagents via pentacoordinate trialkylaluminum complexes

被引：14

作者：

Ooi, T ^{[1
]}

Furuya, M ^{[1
]}

Maruoka, K ^{[1
]}

机构：

[1] Hokkaido Univ, Dept Chem, Grad Sch Sci, Sapporo, Hokkaido 0600810, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 08期

关键词：

D O I：

10.1246/cl.1998.817

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new organoaluminum-promoted selective alkylation of 3,3,3-trifluoropropene oxide (TFPO) with several nucleophiles has been developed which involves the chelation-activated addition to fluoro epoxides via pentacoordinate trialkylaluminum complexes.

引用

页码：817 / 818

页数：2

共 23 条

[1] [Anonymous], 1991, Fluorine in Bioorganic Chemistry
[2] Banks R. E., 1979, ORGANOFLUORINE CHEM
[3] Banks R.E., 1994, ORGANOFLUORINE CHEM
[4] FURUHASHI K, 1992, CHIRALITY IND
[5] REMARKABLE DEPENDENCY OF DIASTEREOSELECTIVITY ON THE SELECTION OF HYDRIDE SOURCES AND LEWIS-ACIDS IN THE REDUCTION OF 2-(TRIFLUOROMETHYL)PROPIOPHENONE
HANAMOTO, T
FUCHIKAMI, T
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (16) : 4969 - 4971
[6] Hudlicky M., 1995, CHEM ORGANIC FLUORIN
[7] Hudlicky M., 1976, Chemistry of Organic Fluorine Compounds. A Laboratory Manual With Comprehensive Literature Coverage
[8] The ring-opening reaction of 3,3,3-trifluoropropene oxide with carbanions: Reaction of alpha-cyanocarbanions
Katagiri, T
Akizuki, M
Kuriyama, T
Shinke, S
Uneyama, K
[J]. CHEMISTRY LETTERS, 1997, (06) : 549 - 550
[9] KHARASCH MS, 1954, GRIGNARD REACTION NO, pCH14
[10] KNUNYANTS IL, 1985, SYNTHESIS FLUOROORGA

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