High Efficiency Quantum Dot Heterojunction Solar Cell Using Anatase (001) TiO2 Nanosheets

被引:154
作者
Etgar, Lioz [1 ]
Zhang, Wei [2 ]
Gabriel, Stefanie [3 ]
Hickey, Stephen G. [3 ]
Nazeeruddin, Md K. [1 ]
Eychmueller, Alexander [3 ]
Liu, Bin [2 ]
Graetzel, Michael [1 ]
机构
[1] Ecole Polytech Fed Lausanne, Dept Sci & Chem Engn, CH-1015 Lausanne, Switzerland
[2] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 117548, Singapore
[3] Tech Univ Dresden, Dept Phys Chem Electrochem, Dresden, Germany
基金
新加坡国家研究基金会; 欧洲研究理事会;
关键词
quantum dots; solar cells; nanosheets; anatase TiO2; PBSE NANOCRYSTALS; PERCENTAGE;
D O I
10.1002/adma.201104497
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This is the first report of using anatase TiO 2 nanosheets with exposed (001) facets in a high-efficiency PbS quantum dot/TiO 2 heterojunction solar cell. The TiO 2 nanosheets have higher conduction band, and surface energy compared to normal anatase (101) TiO 2 nanoparticles. This PbS QD/TiO 2 heterojunction solar cell produces power conversion efficiency of 4.7% which is one of the highest reported in literature. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:2202 / 2206
页数:5
相关论文
共 29 条
  • [1] Depleted Bulk Heterojunction Colloidal Quantum Dot Photovoltaics
    Barkhouse, D. Aaron R.
    Debnath, Ratan
    Kramer, Illan J.
    Zhitomirsky, David
    Pattantyus-Abraham, Andras G.
    Levina, Larissa
    Etgar, Lioz
    Graetzel, Michael
    Sargent, Edward H.
    [J]. ADVANCED MATERIALS, 2011, 23 (28) : 3134 - +
  • [2] Hybrid solar cells from regioregular polythiophene and ZnO nanoparticles
    Beek, Waldo J. E.
    Wienk, Martijn M.
    Janssen, Rene A. J.
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (08) : 1112 - 1116
  • [3] Ambient-Processed Colloidal Quantum Dot Solar Cells via Individual Pre-Encapsulation of Nanoparticles
    Debnath, Ratan
    Tang, Jiang
    Barkhouse, D. Aaron
    Wang, Xihua
    Pattantyus-Abraham, Andras G.
    Brzozowski, Lukasz
    Levina, Larissa
    Sargent, Edward H.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (17) : 5952 - +
  • [4] Ultrabright PbSe magic-sized clusters
    Evans, Christopher M.
    Guo, Li
    Peterson, Jeffrey J.
    Maccagnano-Zacher, Sara
    Krauss, Todd D.
    [J]. NANO LETTERS, 2008, 8 (09) : 2896 - 2899
  • [5] n-Type Transition Metal Oxide as a Hole Extraction Layer in PbS Quantum Dot Solar Cells
    Gao, Jianbo
    Perkins, Craig L.
    Luther, Joseph M.
    Hanna, Mark C.
    Chen, Hsiang-Yu
    Semonin, Octavi E.
    Nozik, Arthur J.
    Ellingson, Randy J.
    Beard, Matthew C.
    [J]. NANO LETTERS, 2011, 11 (08) : 3263 - 3266
  • [6] Quantum Dot Size Dependent J-V Characteristics in Heterojunction ZnO/PbS Quantum Dot Solar Cells
    Gao, Jianbo
    Luther, Joseph M.
    Semonin, Octavi E.
    Ellingson, Randy J.
    Nozik, Arthur J.
    Beard, Matthew C.
    [J]. NANO LETTERS, 2011, 11 (03) : 1002 - 1008
  • [7] Air-stable all-inorganic nanocrystal solar cells processed from solution
    Gur, I
    Fromer, NA
    Geier, ML
    Alivisatos, AP
    [J]. SCIENCE, 2005, 310 (5747) : 462 - 465
  • [8] Synthesis of Titania Nanosheets with a High Percentage of Exposed (001) Facets and Related Photocatalytic Properties
    Han, Xiguang
    Kuang, Qin
    Jin, Mingshang
    Xie, Zhaoxiong
    Zheng, Lansun
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (09) : 3152 - +
  • [9] Colloidal PbS nanocrystals with size-tunable near-infrared emission: Observation of post-synthesis self-narrowing of the particle size distribution
    Hines, MA
    Scholes, GD
    [J]. ADVANCED MATERIALS, 2003, 15 (21) : 1844 - 1849
  • [10] Hybrid nanorod-polymer solar cells
    Huynh, WU
    Dittmer, JJ
    Alivisatos, AP
    [J]. SCIENCE, 2002, 295 (5564) : 2425 - 2427