Facile intermolecular aromatic C-F bond activation reactions of [Ru(dmpe)(2)H-2] (dmpe=Me(2)PCH(2)CH(2)PMe(2))

被引：72

作者：

Whittlesey, MK ^{[1
]}

Perutz, RN ^{[1
]}

Moore, MH ^{[1
]}

机构：

[1] UNIV YORK,DEPT CHEM,YORK YO1 5DD,N YORKSHIRE,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 06期

关键词：

D O I：

10.1039/cc9960000787

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

cis-[Ru(dmpe)(2)H-2] reacts at -78 degrees C with hexafluorobenzene to generate the pentafluorophenyl hydride complex, trans-[Ru(dmpe)(2)(C6F5)H]; reaction also takes place with C6F5H, C6F5CF3, C6F5OCH3, 1,2,3,4-C6F4H2 and 1,2,3-C6F3H3 to yield products from C-F insertion exclusively.

引用

页码：787 / 788

页数：2

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