Structural effects of solvents on the breathing of metal-organic frameworks:: An in situ diffraction study

被引：188

作者：

Millange, Franck ^{[1
]}

Serre, Christian ^{[1
]}

Guillou, Nathalie ^{[1
]}

Ferey, Gerard ^{[1
]}

Walton, Richard I. ^{[2
]}

机构：

[1] Univ Versailles St Quentin En Yvelines, CNRS, UMR 8180, Inst Lavoisier, F-78035 Versailles, France

[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 22期

关键词：

host-guest systems; metal-organic frameworks; nanoporous materials; nanostructures; organic-inorganic hybrid composites;

D O I：

10.1002/anie.200705607

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Breathing space: Time-resolved diffraction studies of the breathing of metal-organic frameworks in the presence of liquids reveal rapid exchange of one guest molecule by another. In some cases this occurs by direct exchange (as shown for water by pyridine), in others with the transient appearance of crystalline intermediates corresponding to partially expanded forms. (Graph Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4100 / 4105

页数：6

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