A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands

被引：361

作者：

Zhang, MB ^{[1
]}

Zhang, J ^{[1
]}

Zheng, ST ^{[1
]}

Yang, GY ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 09期

关键词：

D O I：

10.1002/anie.200461424

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lanthanide oxides as sources of lanthanides provided 3D coordination polymers under hydrothermal conditions in which distinct [Ln14, (μ6-O)(μ3-OH)20(H2O) 8]20+ (Ln = Y, Gd, Dy) clusters are linked to two different types of copper centers through isonicotinate ligands. The unprecedented 3D network topology of. these isostructural compounds is exemplified for Ln = Gd in the picture, which reveals the presence of 1D channels along the c axis. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1385 / 1388

页数：4

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