Involving metals in halogen-halogen interactions:: second-sphere Lewis acid ligands for perhalometallate ions (M-X•••X′-C)

被引：97

作者：

Brammer, L ^{[1
]}

Espallargas, GM ^{[1
]}

Adams, H ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

CRYSTENGCOMM | 2003年 / 5卷

关键词：

D O I：

10.1039/b310412e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lewis-acidic halocarbon groups (X-C) serve as effective second-sphere ligands for perhalometallate ions and provide an alternative means to hydrogen bonds for developing the supramolecular chemistry of such ions, exemplified here by short directional M - X...X' - C halogen bond linkages used in conjunction with hydrogen bonds for crystal synthesis.

引用

页码：343 / 345

页数：3

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