Synthesis of an Attapulgite Clay@Carbon Nanocomposite Adsorbent by a Hydrothermal Carbonization Process and Their Application in the Removal of Toxic Metal Ions from Water

被引:246
作者
Chen, Li-Feng
Lang, Hai-Wei
Lu, Yang
Cui, Chun-Hua
Yu, Shu-Hong [1 ]
机构
[1] Univ Sci & Technol China, Div Nanomat & Chem, Hefei Natl Lab Phys Sci Microscale, Dept Chem, Hefei 230026, Peoples R China
基金
对外科技合作项目(国际科技项目); 中国国家自然科学基金;
关键词
AQUEOUS-SOLUTION; HEXAVALENT CHROMIUM; ACTIVATED CARBON; WASTE-WATER; LEAD; ADSORPTION; CR(VI); SURFACE; CADMIUM; BIOMASS;
D O I
10.1021/la2017165
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new kind of attapulgite clay@carbon (ATP@C) nanocomposite adsorbent has been synthesized by a one-pot hydrothermal carbonization process under mild conditions using two cheap, ecofriendly materials (i.e., attapulgite clay (ATP), which is a magnesium aluminum silicate that is abundant in nature, and glucose, which is a green chemical obtained from biomass), Compared to carbon-based materials, this new ATP@C nanocomposite exhibits a high adsorption ability for Cr(VI) and Pb(II) ions with maximum adsorption capacities of 177.74 and 263.83 mg.g(-1) respectively. The results demonstrate that this nanocomposite is an exceptionally promising candidate as a low-cost, sustainable, and effective adsorbent for the removal of toxic ions from water.
引用
收藏
页码:8998 / 9004
页数:7
相关论文
共 51 条
[21]   Fast removal and recovery of Cr(VI) using surface-modified jacobsite (MnFe204) nanoparticles [J].
Hu, J ;
Lo, IMC ;
Chen, GH .
LANGMUIR, 2005, 21 (24) :11173-11179
[22]   Removal of chromium from aqueous solution by using oxidized multiwalled carbon nanotubes [J].
Hu, Jun ;
Chen, Changlun ;
Zhu, Xiaoxiang ;
Wang, Xiangke .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 162 (2-3) :1542-1550
[23]  
JEROME O, 1988, CHROMIUM NATURAL HUM
[24]   Removal of trivalent and hexavalent chromium by seaweed biosorbent [J].
Kratochvil, D ;
Pimentel, P ;
Volesky, B .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1998, 32 (18) :2693-2698
[25]   THE ADSORPTION OF GASES ON PLANE SURFACES OF GLASS, MICA AND PLATINUM. [J].
Langmuir, Irving .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1918, 40 :1361-1403
[26]   CARCINOGENICITY AND MUTAGENICITY OF CHROMIUM COMPOUNDS - THE ASSOCIATION BETWEEN BRONCHIAL METAPLASIA AND NEOPLASIA [J].
LEVY, LS ;
VENITT, S .
CARCINOGENESIS, 1986, 7 (05) :831-835
[27]  
LIANG H, UNPUB
[28]   Preparation of well-defined star polymer from hyperbranched macroinitiator based attapulgite by surface-initiated atom transfer radical polymerization technique [J].
Liu, Peng ;
Wang, Tingmei .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (01) :97-102
[29]   Carbon spheres/activated carbon composite materials with high Cr(VI) adsorption capacity prepared by a hydrothermal method [J].
Liu, Shouxin ;
Sun, Jian ;
Huang, Zhanhua .
JOURNAL OF HAZARDOUS MATERIALS, 2010, 173 (1-3) :377-383
[30]   Sorption of cadmium and lead from aqueous solutions by spent grain [J].
Low, KS ;
Lee, CK ;
Liew, SC .
PROCESS BIOCHEMISTRY, 2000, 36 (1-2) :59-64