Solid-state NMR studies of weak interactions in supramolecular systems

被引:98
作者
Chierotti, Michele R. [1 ]
Gobetto, Roberto [1 ]
机构
[1] Univ Turin, Dipartimento Chim IFM, Via P Giuria 7, I-10125 Turin, Italy
关键词
D O I
10.1039/b711551b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The field of application of solid-state NMR to the study of supramolecular systems is growing rapidly, with many research groups involved in the development of techniques for the study of crystalline and amorphous phases. This Feature Article aims to provide an overview of the recent contributions of our research group to this. eld, paying particular attention to the study of the weak interactions such as hydrogen bonds in supramolecular systems through solid-state NMR investigations. The structure and dynamic behaviour of selected host - guest systems will be also discussed.
引用
收藏
页码:1621 / 1634
页数:14
相关论文
共 167 条
[11]   Solid state 15N NMR and theoretical studies of primary and secondary geometric H/D isotope effects on low-barrier NHN-hydrogen bonds [J].
Benedict, H ;
Limbach, HH ;
Wehlan, M ;
Fehlhammer, WP ;
Golubev, NS ;
Janoschek, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (12) :2939-2950
[12]   Hydrogen/deuterium isotope effects on the N-15 NMR chemical shifts and geometries of low-barrier hydrogen bonds in the solid state [J].
Benedict, H ;
Hoelger, C ;
AguilarParrilla, F ;
Fehlhammer, WP ;
Wehlan, M ;
Janoschek, R ;
Limbach, HH .
JOURNAL OF MOLECULAR STRUCTURE, 1996, 378 (01) :11-16
[13]   CORRELATIONS BETWEEN PROTON CHEMICAL-SHIFT TENSORS, DEUTERIUM QUADRUPOLE COUPLINGS, AND BOND DISTANCES FOR HYDROGEN-BONDS IN SOLIDS [J].
BERGLUND, B ;
VAUGHAN, RW .
JOURNAL OF CHEMICAL PHYSICS, 1980, 73 (05) :2037-2043
[14]   Intramolecular O-H center dot center dot center dot O hydrogen bonds assisted by resonance. Correlation between crystallographic data and H-1 NMR chemical shifts [J].
Bertolasi, V ;
Gilli, P ;
Ferretti, V ;
Gilli, G .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1997, (05) :945-952
[15]   N-15 MAGNETIC-RESONANCE SPECTROSCOPY - NATURAL-ABUNDANCE N-15 SPECTRA OF SOME 2-AMINO-2-DEOXY-D-HEXOSE DERIVATIVES [J].
BOTTO, RE ;
ROBERTS, JD .
JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (13) :2247-2249
[16]   Crystal engineering, where from? Where to? [J].
Braga, D .
CHEMICAL COMMUNICATIONS, 2003, (22) :2751-2754
[17]   Reactions between or within molecular crystals [J].
Braga, D ;
Grepioni, F .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (31) :4002-4011
[18]   Hydrogen bonding interactions between ions: A powerful tool in molecular crystal engineering [J].
Braga, D ;
Maini, L ;
Polito, M ;
Grepioni, F .
SUPRAMOLECULAR ASSEMBLY VIA HYDROGEN BONDS II, 2004, 111 :1-+
[19]   Mechanochemical preparation of hydrogen-bonded adducts between the diamine 1,4-diazabicyclo [2.2.2] octane and dicarboxylic acids of variable chain length: An x-ray diffraction and solid-state NMR study [J].
Braga, D ;
Maini, L ;
de Sanctis, G ;
Rubini, K ;
Grepioni, F ;
Chierotti, MR ;
Gobetto, R .
CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (22) :5538-5548
[20]   Organometallic polymorphism and phase transitions [J].
Braga, D ;
Grepioni, F .
CHEMICAL SOCIETY REVIEWS, 2000, 29 (04) :229-238