[Ni{(CH3)2SO}6]I4, a redetermination and reinterpretation

被引：21

作者：

Long, DL ^{[1
]}

Hu, HM ^{[1
]}

Chen, JT ^{[1
]}

Huang, JS ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270198013055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of the title polyiodide compound, hexakis(dimethyl sulfoxide-O)nickel(II) tetraiodide, [Ni(C2H6OS)(6)]I-4, has been redetermined. The compound comprises discrete [Ni{(CH3)(2)SO}(6)](2+) cations and I-4(2-) anions. The polyhedron around the six-coordinate Ni atom is a distorted octahedron with the metal atom on a (3) over bar position and six equivalent Ni-O distances of 2.077 (2) Angstrom. The linear uncoordinated centrosymmetric I-4(2-) polyiodide ion represents a rare example of a tetraiodide ion. It exhibits a central I-I bond of 2.848(1) Angstrom and two terminal I-I bonds of 3.342 (2) Angstrom.

引用

页码：339 / 341

页数：3