Methyl modified MOF-5: a water stable hydrogen storage material

被引：223

作者：

Yang, Jie ^{[1
]}

Grzech, Anna ^{[2
]}

Mulder, Fokko M. ^{[2
]}

Dingemans, Theo J. ^{[1
]}

机构：

[1] Delft Univ Technol, Fac Aerosp Engn, Delft, Netherlands

[2] Delft Univ Technol, Fac Sci Appl, Dept Radiat Radionuclides & Reactors, NL-2629 JB Delft, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 18期

关键词：

METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; DRUG-DELIVERY; ADSORPTION; FUNCTIONALIZATION; SITES; STABILITY;

D O I：

10.1039/c1cc11054c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Water stable methyl modified MOF-5s have been synthesized via a solvothermal route. Methyl- and 2,5-dimethyl-modified MOF-5s show the same topology and hydrogen uptake capability as that of MOF-5. The H(2) uptake capacity of MOF-5, however, drops rapidly when exposed to the ambient air, whereas the H(2) uptake capacities of the methyl modified MOF-5s remain stable for 4 days.

引用

页码：5244 / 5246

页数：3

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