2D structure with rectangular grids woven by coordination chains and pseudo-metal wires

被引：18

作者：

Zhang, HX ^{[1
]}

Kang, BS ^{[1
]}

Deng, LR ^{[1
]}

Ren, C ^{[1
]}

Su, CY ^{[1
]}

Chen, ZN ^{[1
]}

机构：

[1] Zhongshan Univ, Sch Chem & Chem Engn, Inst Phys Chem, Guangzhou 510275, Guangdong, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 01期

基金：

中国国家自然科学基金;

关键词：

cyanide complex; coordination polymer; Ag-Ag interactions; metal wire;

D O I：

10.1016/S1387-7003(00)00191-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A heterometallic assembly, [{Cd(en)(2)Ag(CN)(2)} {Ag(CN)(2)}](n), has been synthesized and structurally characterized. The 2D layered structure is constructed by interweaving the coordination chains of {Cd(en)(2)Ag(CN)(2)}(+) containing Cd-N equivalent toC-Ag linkage with the pseudo-metal wires formed by the anions [Ag(CN)(2)](-) and Ag(I) of the chains through Ag-Ag interactions. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：41 / 44

页数：4

共 31 条

[1] The first structurally characterized discrete dinuclear μ-cyano hexacyanoferrate complex [J].