Donor/Acceptor Indenoperylene Dye for Highly Efficient Organic Dye-Sensitized Solar Cells

被引：544

作者：

Yao, Zhaoyang ^{[1
,2
]}

Zhang, Min ^{[1
]}

Wu, Heng ^{[1
]}

Yang, Lin ^{[1
,2
]}

Li, Renzhi ^{[1
]}

Wang, Peng ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 11期

基金：

美国国家科学基金会;

关键词：

N-ANNULATED PERYLENE; CHARGE-TRANSFER DYNAMICS; NANOCRYSTALLINE TIO2; LIGHT-ABSORPTION; PHOTOVOLTAIC PERFORMANCES; RUTHENIUM SENSITIZER; RECOMBINATION; ELECTROLYTE; PORPHYRINS; DESIGN;

D O I：

10.1021/jacs.5b01537

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An N-annulated indenoperylene electrondonor decorated with photochemically inactive segments is synthesized and further conjugated via triple bond with electron-acceptor benzothiadiazolylbenzoic acid for a metal-free donor/acceptor dye. Without use of any coadsorbate, the judiciously tailored indenoperylene dye achieves a high-power conversion efficiency of 12.5% under irradiance of 100 mW cm(-2) AM1.5G sunlight.

引用

收藏

页码：3799 / 3802

页数：4

相关论文

共 69 条

[1] Photodriven heterogeneous charge transfer with transition-metal compounds anchored to TiO2 semiconductor surfaces [J].

Ardo, Shane ;

Meyer, Gerald J. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) :115-164

[2] Titanium Dioxide Nanomaterials for Photovoltaic Applications [J].

Bai, Yu ;

Mora-Sero, Ivan ;

De Angelis, Filippo ;

Bisquert, Juan ;

Wang, Peng .

CHEMICAL REVIEWS, 2014, 114 (19) :10095-10130

[3] A NEW MIXING OF HARTREE-FOCK AND LOCAL DENSITY-FUNCTIONAL THEORIES [J].

BECKE, AD .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (02) :1372-1377

[4] Highly Efficient Mesoscopic Dye-Sensitized Solar Cells Based on Donor-Acceptor-Substituted Porphyrins [J].

Bessho, Takeru ;

Zakeeruddin, Shaik M. ;

Yeh, Chen-Yu ;

Diau, Eric Wei-Guang ;

Graetzel, Michael .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (37) :6646-6649

[5] Organic dye-sensitized solar cells with a cobalt redox couple: influences of π-linker rigidification and dye-bath solvent selection [J].

Cai, Ning ;

Li, Renzhi ;

Wang, Yinglin ;

Zhang, Min ;

Wang, Peng .

ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (01) :139-147

[6] A Broadly Absorbing Perylene Dye for Solid-State Dye-Sensitized Solar Cells [J].

Cappel, Ute B. ;

Karlsson, Martin H. ;

Pschirer, Neil G. ;

Eickemeyer, Felix ;

Schoeneboom, Jan ;

Erk, Peter ;

Boschloo, Gerrit ;

Hagfeldt, Anders .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (33) :14595-14597

[7] Highly Efficient Light-Harvesting Ruthenium Sensitizer for Thin-Film Dye-Sensitized Solar Cells [J].

Chen, Chia-Yuan ;

Wang, Mingkui ;

Li, Jheng-Ying ;

Pootrakulchote, Nuttapol ;

Alibabaei, Leila ;

Ngoc-le, Cevey-ha ;

Decoppet, Jean-David ;

Tsai, Jia-Hung ;

Graetzel, Carole ;

Wu, Chun-Guey ;

Zakeeruddin, Shaik M. ;

Graetzel, Michael .

ACS NANO, 2009, 3 (10) :3103-3109

[8] Dye mediated charge recombination dynamics in nanocrystalline TiO2 dye sensitized solar cells [J].

Clifford, John N. ;

Martinez-Ferrero, Eugenia ;

Palomares, Emilio .

JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (25) :12415-12422

[9] Sensitizer molecular structure-device efficiency relationship in dye sensitized solar cells [J].

Clifford, John N. ;

Martinez-Ferrero, Eugenia ;

Viterisi, Aurelien ;

Palomares, Emilio .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (03) :1635-1646

[10] Energies, structures, and electronic properties of molecules in solution with the C-PCM solvation model [J].

Cossi, M ;

Rega, N ;

Scalmani, G ;

Barone, V .

JOURNAL OF COMPUTATIONAL CHEMISTRY, 2003, 24 (06) :669-681

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