Supercritical carbon dioxide as a reaction medium for enzymatic kinetic resolution of P-chiral hydroxymethanephosphinates

被引：25

作者：

Albrycht, M

Kielbasinski, P

Drabowicz, J

Mikolajczyk, M

Matsuda, T

Harada, T

Nakamura, K

机构：

[1] Polish Acad Sci, Ctr Mol & Macromol Studies, Dept Hetoroorgan Chem, PL-90363 Lodz, Poland

[2] Tokyo Inst Technol, Dept Bioengn, Midori Ku, Yokohama, Kanagawa 2268501, Japan

[3] Ryukoku Univ, Fac Sci & Technol, Dept Mat Chem, Shiga 5202194, Japan

[4] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan

来源：

TETRAHEDRON-ASYMMETRY | 2005年 / 16卷 / 11期

基金：

日本学术振兴会;

关键词：

D O I：

10.1016/j.tetasy.2005.05.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Kinetic resolution of racemic P-chiral hydroxymethanephosphinates via their lipase-promoted acetylation in supercritical carbon dioxide as the reaction medium was for the first time investigated Under various conditions. The reactivity and selectivity could be controlled by changing the pressure. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：2015 / 2018

页数：4

共 13 条

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