Host-guest interactions: ferrocene in KY zeolite

被引：10

作者：

Kaiser, CT

Gubbens, PCM

Kemner, E

Overweg, AR

Jayasooriya, UA

Cottrell, SP

机构：

[1] Delft Univ Technol, Interfacultair Reactor Inst, NL-2629 JB Delft, Netherlands

[2] Univ E Anglia, Sch Chem Sci, Norwich NR4 7TJ, Norfolk, England

[3] Rutherford Appleton Lab, ISIS Facil, Didcot OX11 0QX, Oxon, England

来源：

CHEMICAL PHYSICS LETTERS | 2003年 / 381卷 / 3-4期

关键词：

D O I：

10.1016/j.cplett.2003.09.072

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Host-guest interactions of ferrocene in KY zeolite were investigated using muon spin relaxation (muSR). Temperature-dependent measurements enable us the determination of the activation parameters for the low energy dynamic processes of,the encapsulated ferrocene. A comparison between the pSR results and the earlier neutron measurements illustrates the advantage of the former technique for probing the lowest unoccupied molecular orbital (LUMO). (C) 2003 Elsevier B.V. All rights reserved.

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页码：292 / 297

页数：6

相关论文

共 12 条

[1] LONGITUDINAL MUON SPIN RELAXATION IN MUONIUM-LIKE SYSTEMS [J].

COX, SFJ ;

SIVIA, DS .

HYPERFINE INTERACTIONS, 1994, 87 (1-4) :971-976

[2] Muon spin rotation and relaxation in magnetic materials [J].

deReotier, PD ;

Yaouanc, A .

JOURNAL OF PHYSICS-CONDENSED MATTER, 1997, 9 (43) :9113-9166

[3] THE DYNAMICS OF RING ROTATION IN FERROCENE, NICKELOCENE AND RUTHENOCENE BY INCOHERENT QUASI-ELASTIC NEUTRON-SCATTERING [J].

GARDNER, AB ;

HOWARD, J ;

WADDINGTON, TC ;

RICHARDSON, RM ;

TOMKINSON, J .

CHEMICAL PHYSICS, 1981, 57 (03) :453-460

[4]

JAYASOORIYA HA, UNPUB J CHEM PHYS

[5] Molecular dynamics of organometallic compounds using mu SR [J].

Jayasooriya, UA ;

Aston, GM ;

Stride, JA .

APPLIED MAGNETIC RESONANCE, 1997, 13 (1-2) :165-171

[6]

Karlsson E. B, 1995, SOLID STATE PHENOMEN

[7] Localization of ferrocene in NaY zeolite by powder x-ray and neutron diffraction [J].

Kemner, E ;

Overweg, AR ;

van Eijck, L ;

Fitch, AN ;

Suard, E ;

de Schepper, IM ;

Kearley, GJ .

JOURNAL OF CHEMICAL PHYSICS, 2002, 116 (24) :10838-10845

[8] The vibrational spectrum of solid ferrocene by inelastic neutron scattering [J].

Kemner, E ;

de Schepper, IM ;

Kearley, GJ ;

Jayasooriya, UA .

JOURNAL OF CHEMICAL PHYSICS, 2000, 112 (24) :10926-10929

[9] Molecular motion of ferrocene in a faujasite-type zeolite: A quasielastic neutron scattering study [J].

Kemner, E ;

de Schepper, IM ;

Schmets, AJM ;

Grimm, H ;

Overweg, AR ;

van Santen, RA .

JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (07) :1560-1562

[10] Ferrocene-zeolite interactions measured by inelastic neutron scattering [J].

Kemner, E ;

Overweg, AR ;

Jayasooriya, UA ;

Parker, SF ;

de Schepper, IM ;

Kearley, GJ .

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2002, 74 (Suppl 1) :S1368-S1370