Active-Metal Template Synthesis of a Molecular Trefoil Knot

被引：121

作者：

Barran, Perdita E. ^{[1
]}

Cole, Harriet L. ^{[1
]}

Goldup, Stephen M. ^{[1
]}

Leigh, David A. ^{[1
]}

McGonigal, Paul R. ^{[1
]}

Symes, Mark D. ^{[1
]}

Wu, Jhenyi ^{[1
]}

Zengerle, Michael ^{[1
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 51期

基金：

英国工程与自然科学研究理事会;

关键词：

chemical topology; click chemistry; self-assembly; supramolecular chemistry; template synthesis; SINGLE-STRANDED-DNA; INTERLOCKED MOLECULES; CHEMICAL TOPOLOGY; TERMINAL ALKYNES; ROTAXANES; CATENANES; SHUTTLES; CONSTRUCTION; COPPER(I); ASSEMBLIES;

D O I：

10.1002/anie.201105012

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tying the knot: The marriage of catalysis and coordination chemistry enables two Cu I ions (red; see picture) to work in partnership for the synthesis of a molecular trefoil knot. One ion entangles an acyclic building block to create a loop in the ligand, and the other gathers the ligand's reactive end-groups, threads the loop, and catalyzes the covalent capture of the knotted architecture by an alkyne-azide "click" reaction. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12280 / 12284

页数：5

共 87 条

[21] [2]Rotaxanes through palladium active-template oxidative Heck cross-couplings
Crowley, James D.
Hanni, Kevin D.
Lee, Ai-Lan
Leigh, David A.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (40) : 12092 - +
[22] Diels-Alder Active-Template Synthesis of Rotaxanes and Metal-Ion-Switchable Molecular Shuttles
Crowley, James D.
Haenni, Kevin D.
Leigh, David A.
Slawin, Alexandra M. Z.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (14) : 5309 - 5314
[23] Active metal template synthesis of rotaxanes, catenanes and molecular shuttles
Crowley, James D.
Goldup, Stephen M.
Lee, Ai-Lan
Leigh, David A.
McBurney, Roy T.
[J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (06) : 1530 - 1541
[24] Molecular knots
Dietrich-Buchecker, C
Colasson, BX
Sauvage, JP
[J]. TEMPLATES IN CHEMISTRY II, 2005, 249 : 261 - 283
[25] STRUCTURE OF A SYNTHETIC TREFOIL KNOT COORDINATED TO 2 COPPER(I) CENTERS
DIETRICHBUCHECKER, CO
GUILHEM, J
PASCARD, C
SAUVAGE, JP
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (10): : 1154 - 1156
[26] A SYNTHETIC MOLECULAR TREFOIL KNOT
DIETRICHBUCHECKER, CO
SAUVAGE, JP
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (02): : 189 - 192
[27] SYNTHESIS OF A DNA KNOT CONTAINING BOTH POSITIVE AND NEGATIVE NODES
DU, SM
SEEMAN, NC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (24) : 9652 - 9655
[28] THE CONSTRUCTION OF A TREFOIL KNOT FROM A DNA BRANCHED JUNCTION MOTIF
DU, SM
SEEMAN, NC
[J]. BIOPOLYMERS, 1994, 34 (01) : 31 - 37
[29] Design and synthesis of porphyrin-containing catenanes and rotaxanes
Faiz, Jonathan A.
Heitz, Valerie
Sauvage, Jean-Pierre
[J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (02) : 422 - 442
[30] Feigel M., 2006, ANGEW CHEM, V118, P5827

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