Metal-Organic Frameworks: A Rapidly Growing Class of Versatile Nanoporous Materials

被引：1250

作者：

Meek, Scott T. ^{[1
]}

Greathouse, Jeffery A. ^{[2
]}

Allendorf, Mark D. ^{[1
]}

机构：

[1] Sandia Natl Labs, Livermore, CA 94551 USA

[2] Sandia Natl Labs, Albuquerque, NM 87123 USA

来源：

ADVANCED MATERIALS | 2011年 / 23卷 / 02期

关键词：

POROUS COORDINATION POLYMERS; HYDROGEN STORAGE; XYLENE ISOMERS; FORCE-FIELD; HYDROTHERMAL SYNTHESIS; MOLECULAR SIMULATION; ELECTRONIC-STRUCTURE; ULTRASONIC SYNTHESIS; ENHANCED ADSORPTION; MICROWAVE SYNTHESIS;

D O I：

10.1002/adma.201002854

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic frameworks (MOFs) represent a new class of hybrid organic-inorganic supramolecular materials comprised of ordered networks formed from organic electron donor linkers and metal cations. They can exhibit extremely high surface areas, as well as tunable pore size and functionality, and can act as hosts for a variety of guest molecules. Since their discovery, MOFs have enjoyed extensive exploration, with applications ranging from gas storage to drug delivery to sensing. This review covers advances in the MOF field from the past three years, focusing on applications, including gas separation, catalysis, drug delivery, optical and electronic applications, and sensing. We also summarize recent work on methods for MOF synthesis and computational modeling.

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页码：249 / 267

页数：19

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