Multivalency-Directed Magic-Ring [2](3)Catenane by Olefin Metathesis

被引：14

作者：

Jiang, Yi ^{[1
,2
]}

Zhu, Xiao-Zhang ^{[1
]}

Chen, Chuan-Feng ^{[1
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 48期

基金：

中国国家自然科学基金;

关键词：

catenanes; dynamic covalent chemistry; macrocycles; multivalency; COMPLEXATION; ROTAXANES; PARAQUAT; HOST; PSEUDOROTAXANE; COOPERATIVITY; AMPLIFICATION; DERIVATIVES; LIGANDS; SYSTEM;

D O I：

10.1002/chem.201002111

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

As if by magic: On the basis of formation of a novel multivalency-directed complex between a trisdialkylammonium strand ion and a triptycene-derived homotritopic host, an interesting magic-ring [2](3)catenane was obtained by reversible olefin metathesis (see scheme). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：14285 / 14289

页数：5

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