A new supramolecular synthon using N-methylaniline.: The crystal structure of the 1:1 adduct of N-methylaniline with 5-nitrofuran-2-carboxylic acid

被引：80

作者：

Lynch, DE ^{[1
]}

Thomas, LC

Smith, G

Byriel, KA

Kennard, CHL

机构：

[1] Coventry Polytech, Sch Nat & Environm Sci, Coventry CV1 5FB, W Midlands, England

[2] Queensland Univ Technol, Sch Phys Sci, Brisbane, Qld 4001, Australia

[3] Univ Queensland, Dept Chem, Brisbane, Qld 4072, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1998年 / 51卷 / 09期

关键词：

D O I：

10.1071/C98072

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of the 1:1 adduct of N-methylaniline with 5-nitrofuran-2-carboxylic acid has been determined by single-crystal X-ray diffraction. Crystals are monoclinic, space group P2(1)/c with Z 4 in a cell of dimensions a 8.467(5), b 6.106(2), c 23.95(1) Angstrom, beta 94.48(3)degrees. The molecules associate in a tetrameric, proton-transfer formation which has potential as a new supramolecular synthon.

引用

页码：867 / 869

页数：3

共 9 条

[1] Self-assembly directed by NH-O hydrogen bonding: A neutron study of a trilayered supramolecular array formed between 1,2-diaminoethane and benzoic acid [J].

Adam, KR ;

Atkinson, IM ;

Davis, RL ;

Lindoy, LF ;

Mahinay, MS ;

McCool, BJ ;

Skelton, BW ;

White, AH .

CHEMICAL COMMUNICATIONS, 1997, (05) :467-468

[2] Extended conformation of putrescine occurring on a center of symmetry in its 1:2 complex with malonic acid [J].

Babu, AM ;

Weakley, TJR ;

Murthy, MRN .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 :365-367

[3] SUPRAMOLECULAR SYNTHONS IN CRYSTAL ENGINEERING - A NEW ORGANIC-SYNTHESIS [J].

DESIRAJU, GR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (21) :2311-2327

[4] Molecular tectonics .3. The simultaneous use of H-bonding and coulomb interactions for the self-assembly of fumaric acid and cyclic bisamidine into one- and two-dimensional molecular networks [J].

Felix, O ;

Hosseini, MW ;

DeCian, A ;

Fischer, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (1-2) :102-104

[5] Molecular cocrystals of carboxylic acids. XXVI - Adducts of the amino-substituted benzoic acids with nitroaromatic Lewis bases: the influence of associative polyfunctional substituents on self-assembly of molecules in cocrystallization processes [J].

Lynch, DE ;

Smith, G ;

Byriel, KA ;

Kennard, CHL .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1997, 50 (10) :977-986

[6]

Sheldrick G.M., 1997, SHELX

[7] The utility of 4-aminobenzoic acid in promotion of hydrogen bonding in crystallization processes: the structures of the cocrystals with halo and nitro substituted aromatic compounds, and the crystal structures of the adducts with 4-nitroaniline (1:1), 4-(4-nitrobenzyl)pyridine (1:2), and (4-nitrophenyl)acetic acid (1:1) [J].

Smith, G ;

Lynch, DE ;

Byriel, KA ;

Kennard, CHL .

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1997, 27 (05) :307-317

[8] Molecular cocrystals of carboxylic acids.: XXVIII -: Nitro-substituted carboxylic acids with Lewis bases:: the crystal structures of the adducts of 3,5-dinitrobenzoic acid with N-methylaniline (1:1), (4-nitrophenyl)acetic acid with cyclohexane-1,4-diamine (2:1), and 5-nitrosalicylic acid with 2-imidazolidone (2:1) [J].

Smith, G ;

Lynch, DE ;

Bott, RC .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1998, 51 (02) :159-164

[9]

WILLIAMS DH, 1973, SPECTROSCOPIC METHOD, P35

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