Synthesis, Structure, Characterization, and Redox Properties of the Porous MIL-68(Fe) Solid

被引：203

作者：

Fateeva, Alexandra ^{[1
]}

Horcajada, Patricia ^{[1
]}

Devic, Thomas ^{[1
]}

Serre, Christian ^{[1
]}

Marrot, Jerome ^{[1
]}

Greneche, Jean-Marc ^{[2
]}

Morcrette, Mathieu ^{[3
]}

Tarascon, Jean-Marie ^{[3
]}

Maurin, Guillaume ^{[4
]}

Ferey, Gerard ^{[1
]}

机构：

[1] Univ Versailles St Quentin Yvelines, CNRS, UMR 8180, Inst Lavoisier, F-78035 Versailles, France

[2] Univ Maine, CNRS, UMR 6087, LPEC, F-72085 Le Mans, France

[3] Univ Picardie Jules Verne, CNRS, LRCS UMR 6007, F-80039 Amiens, France

[4] Univ Montpellier 2, CNRS, UMR 5253, Inst Charles Gerhardt Montpellier, F-34095 Montpellier, France

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 24期

关键词：

Metal-organic frameworks; Iron; Microporous materials; Redox activity; Polymorphism; METAL-ORGANIC-FRAMEWORKS; IN-SITU DIFFRACTION; RETICULAR SYNTHESIS; BUILDING-BLOCKS; DRUG-DELIVERY; TOPOLOGY; TEREPHTHALATE; ADSORPTION; BENZENEDICARBOXYLATE; SORPTION;

D O I：

10.1002/ejic.201000486

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new porous Fe-III-based MOF, formulated Fe(OH)(BDC)center dot (dmf)(x) with x approximate to 1.1 and presenting the MIL-68 topology, was prepared by reaction of an iron(III) salt and terephthalic acid (H2BDC) in N,N'-dimethylformamide (dmf) under acidic conditions. The structure and properties of this solid were studied by means of X-ray diffraction, thermogravimetric analysis, nitrogen sorption, Fe-57 Mossbauer spectrometry, and electrochemical lithium insertion.

引用

页码：3789 / 3794

页数：6

共 43 条

[1] Activation of the metal-organic framework MIL-47 for selective adsorption of xylenes and other difunctionalized aromatics [J].