Chemical aspects of self-etching enamel-dentin adhesives: A systematic review

被引:465
作者
Moszner, N [1 ]
Salz, U [1 ]
Zimmermann, J [1 ]
机构
[1] Ivoclar Vivadent AG, Res & Dev, FL-9494 Schaan, Liechtenstein
关键词
dental adhesives; hydrolytic stability; adhesive monomers; phosphonic acids; polymerizable phosphates; cross-linkers; methacrylates; bis(acrylamide)s;
D O I
10.1016/j.dental.2005.05.001
中图分类号
R78 [口腔科学];
学科分类号
1003 ;
摘要
Objectives: The paper gives an overview on the components and the Dental adhesives; polymer chemical aspects of currently used self-etching enamel-dentin primers/adhesives. In addition, the contribution of new adhesives monomers and cross-linkers exhibiting enhanced hydrolytic stability than methacrylates to improve the performance of single-bottle adhesives is discussed. Sources: Information from original scientific papers or reviews about enamel-dentin adhesives, the patent literature concerning dental adhesives and manufacturer information of commercial self-etching adhesives were included in this review. Data: The most efficient self-etching enamel-dentin adhesives are based on strongly acidic adhesive monomers, containing dihydrogenphosphate, phosphonic acids or carboxylic acid groups. Serious problems of single-bottle water-based, strongly acidic self-etching enamel-dentin adhesives arise both from the hydrolytic instability of the methacrylate monomers used and the side reaction of the applied initiator components. Conclusions: The stability of the self-etching enamel-dentin adhesives can be improved by using new acrylic ether phosphonic acids or mono- or difunctional acrytamides, while more stable and compatible components have to be developed in the future. (c) 2005 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:895 / 910
页数:16
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