Palladium(0)-catalyzed hydroalkoxylation of hexafluoropropene: Synthesis of hydrofluoroethers under neutral conditions

被引：36

作者：

Matsukawa, Y ^{[1
]}

Mizukado, J ^{[1
]}

Quan, HD ^{[1
]}

Tamura, M ^{[1
]}

Sekiya, A ^{[1
]}

机构：

[1] Natl Inst AIST, Res Inst Sustainable Chem Innovat, Tsukuba, Ibaraki 3058565, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 07期

关键词：

alcohols; fluorinated alkenes; green chemistry; hydroalkoxylation; palladium;

D O I：

10.1002/anie.200462200

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

No vinyl ether by-products are formed in the palladium(0)-complex catalyzed hydroalkoxylation of hexafluoropropene (see scheme). Saturated hydrofluoro-ethers are selectively synthesized with alcohols or phenols under neutral conditions in the presence of [Pd(PPh3)4]/dppb. dppb = 1,4-bis(diphenylphosphanyl) butane. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1128 / 1130

页数：3

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