'Anti-Wacker'-type hydroalkoxylation of diynes catalyzed by palladium(0)

被引：38

作者：

Camacho, DH ^{[1
]}

Saito, S ^{[1
]}

Yamamoto, Y ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 06期

关键词：

D O I：

10.1016/S0040-4039(01)02318-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The regioselective trans addition of acidic alcohols to conjugated diynes via a Pd(0)-diyne intermediate to give the alkoxylated enyne product, illustrates the first catalytic report involving electrophilic addition to unsaturated bonds by Pd(0). (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：1085 / 1088

页数：4

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